Журнал Сибирского федерального университета
Journal of Siberian Federal University
Химия
Chemistry
Редакционный совет
академик РАН Е.А.Ваганов
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Editorial Advisory Board
Chairman:
Eugene A. Vaganov
Members:
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Editorial Board:
Editor-in-Chief:
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Редактор И.А. Вейсиг Корректор Т.Е. Бастрыгина
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Подписано в печать 27.08.2008 г. Формат 19х27. Усл. печ. л. 10,6.
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CONTENTS / СОДЕРЖАНИЕ
Valentina V. Simonova, Tatyana G. Shendrik,
Nikolai V. Chesnokov, Boris N. Kuznetsov
Influence of Copper Acetate on the Thermochemical Transformations
of Hydrolytic Lignin and its Mixtures with Oil Slimes
– 215 –
Boris N. Kuznetsov, Vladimir I. Kovalchuk,
Nadezhda M. Mikova, Nikolai V. Chesnokov,
Liliya V. Naimushina
Properties in CO Hydrogenation of the Nano-Catalysts Produced
by Supporting Iron Carbonyls on SiO2
– 225 –
Анатолий В. Чубаров, Наталья В. Белоусова,
Алла С. Казаченко, Владимир В. Максименко
p=“2"%!е…,е .леме…2…%L “е!/ " “,“2ем=. S - H2
– 235 –
O - OHÀëåêñàíäð
А. Кузубов, Мария А. Раимова,
Мария В. Сержантова, Татьяна А. Кожевникова,
Александр С. Федоров
Šе%!е2,че“*%е
.ем%“%!Kц,, "%д%!%д= …=…%2!3K=м, “%“2="= MgB2
– 242 –
Руслан Ф. Мулагалеев, Сергей Д. Кирик,
Николай Н. Головн¸в
`це2=2/ C=лл=д, : м%ле*3л !…=
C!е"!=?е…,
– 249 –
“.ем= "ƒ=,м…%г%
- S22008
1 (3)
,““лед%"=…,е C!%це““= д,““%ц,=2,"…%L
Стр.1
Editorial board for Chemistry:
Nikolai V. Chesnokov
Lubov ’ K. Altunina
Natalia G. Bazarnova
Vasiliy A. Babkin
Vicente Cebolla
Viktor M. Denisov
Zinfer R. Ismagilov
Sergey V. Kachin
Sergey D. Kirik
Wolfgang Klose
Vladimir I. Kovalchuk
Vladimir A. Likholobov
Yuri L. Mikhlin
Gennady L. Pashkov
Anatoly I. Rubailo
Tatyana V. Ryazanova
Vladimir A. Sobyanin
Valeri E. Tarabanko
Tatyana G. Shendrik
Maxim L. Shchipko
Jean V. Weber
Юлия Н. Зайцева, Елена Н. Лындина,
Игорь С. Якимов, Сергей Д. Кирик
n“%Kе……%“2, *!,“2=лл,ƒ=ц,, *=льц,L“%де!›=?,. -=ƒ "
%.л=›де……/. C!%K=. .ле*2!%л,2= C!%,ƒ"%д“2"= =люм,…,
– 260 –
Лидия Г. Бондарева, Ольга П. Калякина
hƒ3че…,е …=*%Cле…, Fe(III) C%г!3›е……/м м=*!%-,2%м
Elodea canadensis =…=л,2,че“*,м, ме2%д=м,: ,%……%L
.!%м=2%г!=-,,, ,%…%ме2!,, , “Cе*2!%-%2%ме2!,,
– 269 –
Татьяна Б. Хлебникова, Зинаида П. Пай,
Борис Н. Кузнецов, Юлия В. Матцат,
Светлана А. Кузнецова, Полина В. Бердникова,
Галина П. Скворцова
j=2=л,2,че“*%е %*,“ле…,е Kе23л,…= , д,=це2=2= Kе23л,…= “
,“C%льƒ%"=…,ем .*%л%г,че“*, Kл=г%C!, 2…%г% %*,“л,2ел
– 277 –
Евгения В. Веприкова, Светлана А. Кузнецова,
Галина П. Скворцова, Максим Л. Щипко
q"%L“2"= , C!,ме…е…,е “%!Kц,%……/. м=2е!,=л%" ,ƒ л3K=
*%!/ Kе!еƒ/
– 286 –
Свидетельство о регистрации СМИ
ПИ № ФС77-28-726 от 29.06.2007 г.
Анна И. Бутылкина, Владимир А. Левданский,
Галина С. Калачева, Борис Н. Кузнецов
u!%м=2%-м=““-“Cе*2!%ме2!,че“*%е ,ƒ3че…,е .,м,че“*%г%
“%“2="= ге*“=…%"%г% .*“2!=*2= *%!/ *ед!=
– 293 –
Стр.2
Valentina V. Simonova, Tatyana G. Shendrik… Infl uence of Copper Acetate on the Thermochemical Transformations…
Journal of Siberian Federal University. Chemistry 3 (2008 1) 215-224
~ ~ ~
УДК 546.652
Infl uence of Copper Acetate
on the Thermochemical Transformations
of Hydrolytic Lignin and its Mixtures with Oil Slimes
Valentina V. Simonovaa
Nikolai V. Chesnokovb,c
, Tatyana G. Shendrika
,
* and Boris N. Kuznetsovb,c
a The Institute of Physical and Organic Chemistry and Coal Chemistry, NAS
Siberian Federal University,
c
70 R. Luxemburg st., Donetsk, 831114 Ukraine
b
79 Svobodny, Krasnoyarsk, 660041 Russia
Institute of Chemistry and Chemical Technology SB RAS,
42 K. Marx st., Krasnoyarsk, 660049 Russia 1
Received 4.08.2008, received in revised form 22.09.2008, accepted 29.09.2008
By using various physical and chemical methods there were studied the thermochemical transformations
of hydrolytic lignin modifi ed with copper and its mixtures with oil slimes. As a result at the accomplished
study there was carried out the selection of the conditions for modifying and thermal activation this
industrial waste providing the production the active carbons with the yield 18-19 wt% and specifi c
surface area of 620 m2
/g.
Keywords: hydrolytic lignin, modifi cation, copper acetate, oil-slime, thermal transformation, active
carbon, structure, propeties.
Introduction
The traditional vegetable raw material
for production porous carbon-based materials
(PCM) is birch wood [1]. The low yield of the
carbonic product
(not more than 12 % of
the
initial raw material mass) encourages the studies
aimed at broadening the raw material sources of
production PCM at the expense of using wood
waste. These are also aimed at developing more
perfect ways of carrying out the pyrolysis and
raw material activation.
To regulate the structure and properties
of carbonic sorbents, there is widely used the
* Corresponding author E-mail address: bnk@icct.ru
1
© Siberian Federal University. All rights reserved
# 215 #
chemical modifi cation of vegetable polymers.
In particular, the processing of
lignocellulose
materials by using various chemical reagents,
such as the acids (H3
PO4
, H3
BO3
, H2
SO4
the alkalis (KOH and others) [5], the salts (ZnCl2
AlCl3
) [2-4],
,
and others) [6, 7], allows to increase the
yield and the specifi c surface of the formed
PCM.
porous
The perspective direction in production
carbonic materials is modifying the
vegetable polymers with the compounds of
transition metals [8-10]. During the pyrolysis of
the modifi ed vegetable materials, at the same time,
Стр.3