Журнал Сибирского федерального университета
Journal of Siberian Federal University
Химия
Chemistry
Редакционный совет
академик РАН Е.А.Ваганов
академик РАН И.И.Гительзон
академик РАН В.Ф.Шабанов
чл.-к. РАН, д-р физ.-мат.наук
А.Г.Дегерменджи
чл.-к. РАН, д-р физ.-мат. наук
В.Л.Миронов
чл.-к. РАН, д-р техн. наук
Г.Л.Пашков
чл.-к. РАН, д-р физ.-мат. наук
В.В.Шайдуров
чл.-к. РАН, д-р физ.-мат. наук
В.В. Зуев
Editorial Advisory Board
Chairman:
Eugene A. Vaganov
Members:
Josef J. Gitelzon
Vasily F. Shabanov
Andrey G. Degermendzhy
Valery L. Mironov
Gennady L. Pashkov
Vladimir V. Shaidurov
Vladimir V. Zuev
Editorial Board:
Editor-in-Chief:
Mikhail I. Gladyshev
Founding Editor:
Vladimir I. Kolmakov
Managing Editor:
Olga F. Alexandrova
Executive Editor for Chemistry:
Boris N. Kuznetsov
CONTENTS / СОДЕРЖАНИЕ
Alexey M. Melnikov and Olga N. Kononova
Kinetics of Simultaneous Recovery of Platinum (II,IV) and
Rhodium (III) from Sulfate-Chloride Solutions on some Anion
Exchangers
– 207 –
Ë.Ò. Äåíèñîâà, Â.Ì. Äåíèñîâ, Ë.Ã. Чумилина
bƒ=,м%деL“2",е !=“Cл="%" Bi2
O3
-SiO2
– 216 –
Â.È. Øàðûïîâ, Ë.È. Ãðèøå÷êî, Ë.Ñ. Òàðàñîâà,
С.В. Барышников, А. Селзард, Б.Н. Кузнецов
h““лед%"=…,е 2е!м,че“*%г% !=ƒл%›е…, %K!=ƒц%" л,г…,…=,
"/деле……/. ,ƒ д!е"е“,…/ %“,…/ !=ƒл,ч…/м, ме2%д=м,
– 221 –
Ä.Ã. Ñëàùèíèí, Þ.À. Àëåìàñîâ, Ä.È. Èëþøêèí,
Â.À. Соколенко, Ì.Ñ. Òîâáèñ, Ñ.Ä. Кирик
pе=*ц,
=л*,л,!%"=…,
…,2!%ƒ%-е…%л%"
– 233 –
С.А. Кузнецова, Г.П. Скворцова,
Å.Ñ. Скурыдина, Þ.Í. Ìàëÿð, Î.À. Ханчич
bл, …,е 3“л%",L =ц,л,!%"=…, C!%C,%…%"%L *,“л%2%L Kе!е“2/
*%!/ Kе!еƒ/ , её =*2,"=ц,, …= "/.%д , “%“2=" .*“2!=*2%"
– 248 –
В.В. Риваненков, С.С. Лалетина, Т.В. Шулимович,
À.Ì. Øîð, Å.À. Øîð, Â.À. Наслузов
Šе%!е2,че“*%е ,ƒ3че…,е =д“%!Kц,, …еK%льш,. ч=“2,ц ƒ%л%2=
…= г,д!%*“,л,!%"=……%L C%"е!.…%“2, %*“,д= =люм,…,
– 257 –
Редактор И.А. Вейсиг Корректор Т.Е. Бастрыгина
Компьютерная верстка Е.В. Гревцовой
Подписано в печать 16.09.2011 г. Формат 84х108/16. Усл. печ. л. 9,0.
Уч.-изд. л. 8,5. Бумага тип. Печать офсетная. Тираж 1000 экз. Заказ 5237.
Отпечатано в ПЦ БИК СФУ. 660041 Красноярск, пр. Свободный, 82a.
Cе!ƒ=ме?е……/.
параc
“е!еK!%м
2011 4 (3)
Стр.1
Editorial board for Chemistry:
Nikolai V. Chesnokov
Lubov ’ K. Altunina
Natalia G. Bazarnova
Vasiliy A. Babkin
Vicente Cebolla
Viktor M. Denisov
Zinfer R. Ismagilov
Sergey V. Kachin
Sergey D. Kirik
Wolfgang Klose
Vladimir I. Kovalchuk
Vladimir A. Likholobov
Yuri L. Mikhlin
Gennady L. Pashkov
Anatoly I. Rubailo
Tatyana V. Ryazanova
Vladimir A. Sobyanin
Valeri E. Tarabanko
Tatyana G. Shendrik
Jean V. Weber
Ï.Î. Êðàñíîâ, À.À. Кузубов
o!,!%д= .,м,че“*%г% “" ƒ/"=…, =2%м%" “*=…д, , 2,2=…= “
*л=“2е!…/м, м%дел м, г!=-е…=, ,“*!,"лё……%г% ,ƒ-ƒ= …=л,ч,
C 2,- , “ем,чле……/. 3гле!%д…/. *%лец
– 269 –
Е.О. Игнатьева, Е.М. Дворянова, И.К. Гаркушин
o!%г…%ƒ,!%"=…,е , .*“Cе!,ме…2=ль…%е C%д2"е!›де…,е
-=ƒ%"%г% *%мCле*“= “,“2ем/ NaF-NaI-Na2
– 276 –
WO4
À.Â. Ñèäîðàê, À.À. Øóáèí,
В.В. Иванов, Н.С. Николаева
q,…2еƒ C%!%ш*%" Zn2
“%ед,…е…,L
SnO4
2е!м%%K!=K%2*%L “%%“=›де……/.
– 285 –
Свидетельство о регистрации СМИ
ПИ № ФС77-28-726 от 29.06.2007 г.
Серия включена в «Перечень ведущих
рецензируемых научных журналов
и изданий, в которых должны
быть опубликованы основные научные
результаты диссертации на
соискание ученой степени доктора и
кандидата наук» (редакция 2010 г.)
È.Â. Îñèïîâà, Ã.À. Ãëóùåíêî, Â.Ã. Èñàêîâà,
Å.À. Гончарова, À.Ñ. Êðûëîâ, Ñ.Ì. Æàðêîâ,
Э.А. Петраковская, Г.Н. Чурилов
h““лед%"=…,е …=…%ч=“2,ц “% “2!3*23!%L ме2=лл,че“*%е д!% $
3гле!%д…= %K%л%ч*=, %K!=ƒ3ю?,.“ C!, Cл=ƒм%.,м,че“*%м
“,…2еƒе " "/“%*%ч=“2%2…%м д3г%"%м !=ƒ! де
– 294 –
Т.А. Фроленко, Е.С. Семиченко,
Ì.Ã. Мельникова, Í.À. Гаврилова, Ã.À. Субоч
q,…2еƒ …,2!%ƒ%- , =м,…%-N-=д=м=…2,лC,!=ƒ%л%"
– 301 –
А.С. Косицына, А.А. Кондрасенко,
Å.Ñ. Семиченко, Ã.À. Субоч
Š=32%ме!, , ,ƒ%ме!, м%…%,м,…%" 3-г,д!%*“,м,…%-2,4Cе…2=…д,%…=
–
307 –
Стр.2
Journal of Siberian Federal University. Chemistry 3 (2011 4) 207-215
~ ~ ~
УДК 541.183 : 543.426
Kinetics of Simultaneous Recovery
of Platinum (II,IV) and Rhodium (III)
from Sulfate-Chloride Solutions
on some Anion Exchangers
Alexey M. Melnikov and Olga N. Kononova*
Siberian Federal University
79 Svobodny, Krasnoyarsk, 660041 Russia 1
Received 2.09.2011, received in revised form 9.09.2011, accepted 16.09.2011
The paper is devoted to the kinetics of sorption concentration of platinum (II,IV) and rhodium (III)
in their simultaneous presence in freshly prepared or stored sulfate-chloride solutions on some
macroporous anion exchangers with different chemical structure.
It was shown that the process rate is high, although it is slightly reduced in case of stored solutions.
The rate of platinum sorption concentration in the presence of rhodium on investigated resins is higher
than of rhodium in the presence of platinum. The sorption process was controlled by gel diffusion for
all the anion exchangers studied.
Keywords: platinum, rhodium, sorption, kinetics of sorption.
Introduction
To date, the growing demand for platinum group metals (PGM) stipulated their intensive mining
and expansion of supplies of secondary raw materials (spent automobile catalysts, catalysts from
chemical
industry, electronic scrap and wastes of ore-dressing plants on noble metal-containing
deposits). Low concentrations of PGM in solutions obtained after breakdown of such raw materials
cause the application of sorption methods, known not only for their effi ciency and selectivity, but also
for environmental safety [1,2]. The successful industrial application of ion exchangers requires not
only investigating their sorption properties, but also their kinetic behavior, as the satisfactory rate is
one of the essential factors for resins’ technological use.
The recovery of PGM from products of processing of secondary raw materials occurs often by
means of sulfuric acid and sulfate solutions. In these solutions, platinum and rhodium exist in the form
of sulfate complexes, which are more kinetically inert, compared to corresponding chloride complexes,
especially of rhodium [1,3]. The sulfate complexes of platinum and rhodium are hardly sorbed and,
* Corresponding author E-mail address: cm2@bk.ru
1
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