Вестник МИТХТ, 2009, т. 4, № 4
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Вестник
МИТХТ
4/2009
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в два месяца
Учредитель
МИТХТ им. М.В.Ломоносова
СОДЕРЖАНИЕ
ИНФОРМАЦИОННЫЕ СООБЩЕНИЯ
В.И. Швец. Пятый Московский международный конгресс
«Биотехнология: состояние и перспективы развития»
ХИМИЯ И ТЕХНОЛОГИЯ ЛЕКАРСТВЕННЫХ ПРЕПАРАТОВ И
БИОЛОГИЧЕСКИ АКТИВНЫХ СОЕДИНЕНИЙ
В.И. Швец. Фосфолипиды в биотехнологиях
Н.В. Новиков, В.В. Старков, К.А. Формировский, Н.А. Брагина,
И.П. Ушакова, А.Ф. Миронов. Синтез и свойства катионных
производных мезо-тетра-(4-пиридил)порфирина
ТЕОРЕТИЧЕСКИЕ ОСНОВЫ ХИМИЧЕСКОЙ ТЕХНОЛОГИИ
В.М. Раева, А.К. Фролкова. Концентрационные зависимости
избыточных молярных теплоемкостей бинарных растворов
Л.А. Серафимов, А.В. Анисимов, К.Ю.Тархов. Некоторые вопросы
массопереноса в бинарных смесях в терминах диффузионной
модели
ХИМИЯ И ТЕХНОЛОГИЯ ОРГАНИЧЕСКИХ ВЕЩЕСТВ
Л.В. Дашко, Д.В. Дмитриев, В.Р. Флид. Особенности кроссальдольной
конденсации ацетальдегида и формальдегида в
присутствии аминокислот и их производных
Главный редактор:
проф. Тимофеев В.С.
Зам. главного редактора:
проф. Фролкова А.К.
проф. Фомичев В.В.
В.Г. Кучеров, А.Ю. Колесников. Метановый путь образования
углеводородов при сверхвысоких параметрах состояния
В.Ф. Третьяков, А.М. Илолов, Н.А. Французова, Р.М. Талышинский.
Изучение сопряженного каталитического дегидрирования
метанола в формальдегид в присутствии перекиси водорода
ХИМИЯ И ТЕХНОЛОГИЯ НЕОРГАНИЧЕСКИХ МАТЕРИАЛОВ
В.В. Апанасенко. Расчѐт материального баланса металлургического
производства с использованием электронных таблиц «Еxcel»
Редакционная коллегия:
доц. Биглов Р.Р.
проф. Дробот Д.В.
проф. Корнюшко В.Ф.
акад. РАН Кузнецов Н.Т.
акад. РАН Мирошников А.И.
проф. Мирошников Ю.П.
проф. Озерин А.Н.
проф. Серафимов Л.А.
проф. Сухорукова С.М.
проф. Тверской В.А.
акад. РАН Цивадзе А.Ю.
акад. РАМН Швец В.И.
доц. Юловская В.Д
И.Д. Бурлаков, А.С. Кашуба, Е.В Пермикина, С.В. Головин,
В.В. Арбенина. Влияние морфологии и полярности поверхности
эпитаксиальных слоев на качество пассивирующего покрытия
и параметры матричных фотоприемных устройств на основе
СdхHg1-хTe
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В.В. Коновалова, Р.М. Закалюкин, Д.В. Дробот, В.В. Фомичев.
Сложные допированные оксиды ниобия с ионной проводимостью 84
СИНТЕЗ И ПЕРЕРАБОТКА ПОЛИМЕРОВ И КОМПОЗИТОВ НА ИХ ОСНОВЕ
И.А. Грицкова, Г.А. Симакова, Н.И. Прокопов, Т.С. Соловьева,
Е.В. Матвеев, А.С. Бирлов. Коллоидно-химические свойства ПАВ
различной природы на межфазных границах мономер/вода
90
С.В. Фомин, Е.С. Широкова. Массоперенос дибутилсебацината
в вулканизаты на основе бутадиен-нитрильных и бутадиен-метилстирольных
каучуков
97
ЭКОЛОГО-ЭКОНОМИЧЕСКИЕ ПРОБЛЕМЫ ХИМИЧЕСКИХ ТЕХНОЛОГИЙ
Е.А. Дѐмчева, В.Б. Люкманов, С.А. Панова, О.В. Макаров.
Научно-технический аутсорсинг как инструмент управления
экологически ориентированным развитием химических предприятий
С.М.
Сухорукова. О решении эколого-экономических проблем
в сфере промышленного природопользования
ЮБИЛЕЙ
© МИТХТ им. М.В. Ломоносова Abstracts
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Вестник МИТХТ, 2009, т. 4, № 4
Review
MITHT
4/2009
Редакция:
Агаянц И.М.
Наумова Ю.А.
Семерня Л.Г.
Середина Г.Д.
CONTENTS
INFORMATION
V.I. Shvets. “The Fifth Moscow International Congress «Biotechnology:
state of the art and prospects of developme»
CHEMISTRY AND TECHNOLOGY OF MEDICAL PRODUCTS AND
BIOLOGICALLY ACTIVE SUBSTANCES
V.I. Shvets. Phospholipids in biotechnologies
N.V. Novikov, V.V. Starkov, K.A. Formirovskiy, N.A. Bragina, I.P.
Ushakova, A.F.Mironov. Synthesis and properties of cationic
derivaties of meso-tetra-(4-pyridyl)porphyrin
THEORETICAL BASED OF CHEMICAL TECHNOLOGY
V.M. Raeva, A.K. Frolkova. Excess molar heat capacities as
function of composition of binary solutions
L.A. Serafimov, A.V. Anisimov, K.Yu. Tarkhov. Some problems of
mass-transfer in binary mixtures in terms of diffusion model
Адрес редакции:
119571, г. Москва,
пр. Вернадского, 86,
к. Л-119
телефон: (495) 936-82-88
e-mail: vestnik@mitht.ru
CHEMISTRY AND TECHNOLOGY OF ORGANIC SUBSTANCES
L.V. Dashko, D.V. Dmitriev, V.R. Flid. Specifics of cross-aldol
condensation of acetaldehyde with formaldehyde in presence of
aminoacids and their derivatives
V.G. Kutcherov, A.Yu. Kolesnikov. Methane route of hydrocarbons
formation at very high pressure and high temperature
V.F.Tretyakov, A.M.Ilolov, N.A.Frantsuzova, R.M.Talyshinsky
Studying of the conjugate catalytics degidration of methanol to
formaldehyde in the presence of hydrogen peroxide
Подписано в печать
17.08.2009 г. Формат 60x90/8.
Бумага офсетная.
Гарнитура Times.
Печать офсетная.
Уч. изд. листов 4,4.
Заказ № 163.
Тираж 500 экз.
CHEMISTRY AND TECHNOLOGY OF INORGANIC MATERIALS
V.V. Apanasenko. The calculation of material balance of metallurgical
production using «Excel»
I.D. Burlakov, A.S. Kashuba, E.V. Permikina, S.V. Golovin,
V.V. Arbenina. The Influence of the Epitaxial Layers Surface
Morphology and Polarity on Quality of Passivating Coating and the
Parameters of Arrays Photosensitive Devices on base CdхHg1-хTe
V.V. Konovalova, R.M. Zakalyukin, D.V. Drobot, V.V. Fomichev.
Сomplex doping niobium oxide with ionic conductivity
Отпечатано с оригинал-макета в
«ГЕЛИОПРИНТ»
119602, Москва, Ак. Анохина, 38, к. 1
SYNTHESIS AND PROCESSING OF POLYMERIC COMPOSITES
I.A. Gritskova, G.A. Simakova, N.I. Prokopov, T.S. Solovyeva, E.V.
Matveev, A.S. Birlov. Colloid-chemical properties of polimermonomer
particles on boundary of monomer/water
S.V. Fomin, E.S. Shirokova. Masstransfusion of dibutylsebacinate in
butadien-acrylonitrylic and butadien-methylstyrolic vulcanizates
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ECOLOGICAL AND ECONOMIC PROBLEMS OF CHEMICAL TECHNOLOGIES
E.A. Demcheva, V.B. Lukmanov, S.A. Panova , O.V. Makarov.
Scientific-technical outsourcing as the management tool of the
ecologically focused development of the chemical enterprises
S.M. Sukhorukova. About the solution of ecological and economic
problems in the field of industrial use of nature
ANNIVERSARY
Abstracts
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«Вестник МИТХТ», 2009, т. 4, № 4
ABSTRACTS
V.I. Shvets. Phospholipids in biotechnologies
The review describes modern concepts of chemical and enzymatic synthesis, isolation of
substances from natural sources, and creation of industrial technologies for obtaining
phospholipids of various molecular types. Data on their structures, biological activities, and the
possibility of using them for the preparation of liposomal forms of drugs are presented
N.V. Novikov, V.V. Starkov, K.A. Formirovskiy, N.A. Bragina, I.P. Ushakova, A.F.Mironov.
Synthesis and properties of cationic derivaties of meso-tetra(4-pyridyl)porphyrin
Synthesis of amphyphilic cationic meso-pyridilsubstituted porphyrins bearing long chain alkyl
groups is described. An improved methods of preparation of tetra- and mono-alkylsubstituted
meso-pyridil porphyrins are proposed. The data porphyrins will be investigated as mesogenic
compounds and in studing of DNA-binding interactions of cationic porphyrins.
V.M. Raeva, A.K. Frolkova. Excess molar heat capacities as function of composition of binary
solutions
The concentration dependences of excess molar heat capacities of binary solutions is
investigated. The projection of the systems behavior in terms of limited information is considered.
The necessity of account of these excess thermodynamic function at the calculation of distillation
is discussed.
L.A. Serafimov, A.V. Anisimov, K.Yu. Tarkhov. Some problems of mass-transfer in binary mixtures
in terms of diffusion model
The analysis of mass-transfer equations used in practice of mass-exchange apparatus calculation
for binary mixtures is carried out. It is showed that these equations are approximate. The accurate
equation of mass-transfer based on diffusion model using linearization is proposed for qualitative
investigations of binary mixtures rectification process
L.V. Dashko, D.V. Dmitriev, V.R. Flid. Specifics of cross-aldol condensation of acetaldehyde with
formaldehyde in presence of aminoacids and their derivatives
Reaction of cross-aldol condensation of acetaldehyde with formaldehyde at presence of
aminoacids and their ether- and benzoil-derivatives were studied in pyridine, N, Ndymethylacetamide,
water and toluene. It was shown that aminoacids are capable to catalyse
cross- and homocondensation of acetaldehyde. The yield of acrolein in presence of aminoacids is
much lower than with use of its derivatives. The selectivity of cross-condensation is dependent
from acid-base properties of catalyst and the reaction media. It is found that the main contribute to
catalysis of cross-condensation is introduced by amino-group of aminoacid and it basic properties
determine the yield of acrolein
V.G. Kutcherov, A.Yu. Kolesnikov. Methane route of hydrocarbons formation at very high pressure
and high temperature.
Results of experimental investigations of synthesis of hydrocarbon systems at high pressure and
different mechanisms of synthesis are discussed. Experimental results presented in this paper
confirm the possibility of synthesis of hydrocarbon at mantle conditions from methane. These
results can be accepted as support for the theory of the abyssal abiotic petroleum origin.
The initiation effect of the main process in direct ethanol dehydration to formaldehyde with
hydrogen peroxide has been discovered. A hypothesis of the reaction mechanism has been
proposed suggesting the conjugate dehydration of methanol with disintegration of hydrogen
peroxide accompanied by the formation of HO2
● radicals.
V.F. Tretyakov, A.M. Ilolov, N.A. Frantsuzova, R.M.Talyshinsk. Studying of the conjugate
catalytics degidration of methanol to formaldehyde in the presence of hydrogen peroxide.
From the studies of the kinetics of methanol conjugate dehydration process, a kinetic model has
been proposed and kinetic parameters calculated. It was discovered that when other substances
like ethane, ethylene were used as initiators the catalyst surface coked rapidly. On the K-1 model
in the presence of hydrogen peroxide (1% in water solution of the initial methanol) the temperature
of the dehydration process reduces by 50-60ºС at 50% formaldehyde yield and allows for the
reaction to be carried out at a temperature of 820-830ºС
V.V. Apanasenko. The calculation of material balance of metal-lurgical production using «Excel»
It has been shown, that for automation of the calculation of material balance of technological
processes one can successfully use Microsoft Excel, which allows to make balance calculations
less laborious, to calculate large quantity of versions easily and thus to choose an optimal variant
for the realization of technical process. Peculiarities of balance schemes made with the use of
“Excel” were considered. An example of the calculation of material balance of the process of gas
purification in production of trichlorosilane is given
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«Вестник МИТХТ», 2009, т. 4, № 4
I.D. Burlakov, A.S. Kashuba, E.V. Permikina, S.V. Golovin, V.V. Arbenina. The influence of the
epitaxial layers surface morphology and polarity on quality of passivating coating and the
parameters of arrays photosensitive devices on base CdхHg1-хTe
The influence of growth surface defects of CdхHg1-хTe epitaxial layers which has been grown by
liquid phase epitaxy on quality of passivating coatings, creating by the method of “the hot wall”, is
investigated. The reason of negative action nonplanarity and а surface defects of CdхHg1-хTe
epitaxial layers on the technological process of the manufacture of photodiodes is established.
The influence of crystallographic polarity of CdхHg1-хTe epitaxial layers on velocity of the CdTe
coating precipitation and surface morphology is discussed
V.V. Konovalova, R.M. Zakalyukin, D.V. Drobot, V.V. Fomichev. Сomplex doping niobium oxide
with ionic conductivity.
The novel compounds Li6MNb4O14 (M = Zn, Mg) have been synthesized and characterized in the
Li2O–MO–Nb2O5 (M = Zn, Mg) system. The synthesized phases were investigated by XRD, DTA
and the chemical analysis. Specific conductivity and energy of activation of each compounds and
the sample that doping by titanium oxide has been found. Comparison of absorption IR–spectra of
investigated compounds and of samples Li6ZnNb4O14 having isotope on lithium and zinc has been
compared.
I.A. Gritskova, G.A. Simakova, N.I. Prokopov, T.S. Solovyeva, E.V. Matveev, A.S. Birlov. Colloidchemical
properties of polimer-monomer particles on boundary of monomer/water
Colloid-chemical properties of surface active substances of different nature on the boundary of
styrene/water, isoprene/water, mixture of styrene and isoprene/water are discussed. It was shown
that the mechanism of creation polymer-monomer particles are depending from composition of
emulsion
S.V. Fomin, E.S. Shirokova. Masstransfusion of dibutylsebacinate in butadien-acrylonitrylic and
butadien-methylstyrolic vulcanizates
The investigation of diffusion of dibutylsebacinate in butadien-acrylonitrylic and butadienmethylstyrolic
vulcanizates was realized. It was shown that diffusion process in butadienacrylonitrylic
vulcanizates isn't stationary. Diffusion coefficients of dibutylsebacinate in butadienacrylonitrylic
and butadien-methylstyrolic vulcanizates was calculated. Parameters describing
compatibility of plasticizer with above named rubbers was determined. Adhesion characteristics
were calculated. It was shown that structures of rubber and plasticizer are influence upon
masstransfusion kinetic
E.A. Demcheva, V.B. Lukmanov, S.A. Panova , O.V. Makarov. Scientific-technical outsourcing as
the management tool of the ecologically focused development of the chemical enterprises.
Outsourcer search stages are defined. The model of the outsourcer selection is offered, allowing
the enterprise to maximize the net present value as a result of research and developmental works
using scientific-technical outsourcing, including solutions on environmental oriented problems
S.M. Sukhorukova. About the solution of ecological and economic problems in the field of
industrial use of nature
The article is dedicated to the search of reasons, which do not allow to provide ecological and
economic efficiency of industrial use of nature. The possibility of transfer to biosphere economy
and cosmic ecology is proposed for consideration
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«Вестник МИТХТ», 2009, т. 4, № 4
Вестник МИТХТ
Журнал выходит один раз в два месяца и публикует обзоры и статьи по
актуальным проблемам химической технологии и смежных наук. Журнал основан в
2006 году. Учредителем журнала является Московская государственная академия
тонкой химической технологии им. М.В. Ломоносова (МИТХТ).
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1. Теоретическим основам химической технологии
2. Химии и технологии органических веществ
3. Химии и технологии лекарственных препаратов и биологически активных
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4. Синтезу и переработке полимеров и композитов на их основе
5. Химии и технологии неорганических материалов
6. Химии и технологии редких и рассеянных элементов
7. Математическим методам и информационным технологиям в химии и
химической технологии
8. Эколого-экономическим проблемам химических технологий.
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