«Вестник МИТХТ», 2009, т. 4, № 1
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Учредитель
МИТХТ им. М.В.Ломоносова
СОДЕРЖАНИЕ
К 175-ЛЕТИЮ Д.И. МЕНДЕЛЕЕВА
Л.Ю. Аликберова. Пeриодический закон и Периодическая
система химических элементов.
А.Ю. Закгейм. Менделеев и Бородин.
А.А. Иванова. О некоторых особенностях мировоззрения
Д.И. Менделеева.
С.М. Сухорукова, А.К. Фролкова, К.К. Нечеухин. Д.И. Менделеев
как основоположник социо-эколого-экономического подхода к
развитию промышленности в России.
ХИМИЯ И ТЕХНОЛОГИЯ ОРГАНИЧЕСКИХ ВЕЩЕСТВ
В.П. Висловский, Р.М. Талышинский, В.Ф. Третьяков, Н.А. Французова,
В.Е. Шейнин. Окислительное дегидрирование изобутана в
изобутен на Ni-V-Sb-алюмооксидном катализаторе.
Ю.Б. Кириллов, Н.М. Клименко. Неэмпирические расчеты
минимальных энергетических путей реакций присоединения
молекулы HF к молекулам ацетилена и метилацетилена.
С.А. Макарова, И.С. Левачева, И.А. Грицкова, М.А. Сакварелидзе,
А.Е. Харлов, С.М. Левачев. Влияние сульфата аммония на свойства
2D пленок, сформированных из полистирольных микросфер.
Главный редактор:
проф. Тимофеев В.С.
Зам. главного редактора:
проф. Фролкова А.К.
проф. Фомичев В.В.
Д.С. Сидоренко, А.В. Вовк, С.А. Кутылев, Г.М. Кузьмичева,
А.Б. Дубовский. Получение и изучение углеродных нанотрубок.
ТЕОРЕТИЧЕСКИЕ ОСНОВЫ ХИМИЧЕСКОЙ ТЕХНОЛОГИИ
М.К. Захаров. Энергозатраты и энергосбережение при
разделении жидких смесей методами перегонки.
Г.А. Носов, М.Е. Уваров, В.М. Мясоеденков. Перекристаллизация
веществ из растворов с применением теплового насоса.
А.А. Смирных. Особенности конструкции измерительной
ячейки ротоционного устройства для измерения вязкости
материала
Редакционная коллегия:
доц. Биглов Р.Р.
проф. Дробот Д.В.
проф. Корнюшко В.Ф.
акад. РАН Кузнецов Н.Т.
акад. РАН Мирошников А.И.
проф. Мирошников Ю.П.
проф. Озерин А.Н.
проф. Серафимов Л.А.
проф. Сухорукова С.М.
проф. Тверской В.А.
акад. РАН Цивадзе А.Ю.
акад. РАМН Швец В.И.
доц. Юловская В.Д.
А.А. Смирных. Усовершенствование вискозиметра Гепплера
для исследования жидких сред, обладающих повышенными
оптической плотностью и вязкостью
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СИНТЕЗ И ПЕРЕРАБОТКА ПОЛИМЕРОВ И КОМПОЗИТОВ НА ИХ ОСНОВЕ
М.А. Полунина, В.А.Тверской, Н.В. Дорофеева. Газоразделительные
свойства мембран с диффузионными слоями из Nалкилированного
поливинилпиридина и его комплексов с
додецилсульфатом натрия.
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Б.В. Покидько, Е.Ф. Буканова, И.А. Туторский, М.Б. Ильина.
Влияние ионов кальция на адсорбцию ионных и неионных
ПАВ на бентоните
А.Н. Трофимов, О.Ю. Брыксина, В.М. Комаров, В.С. Копытин,
Г.А. Симакова, И.Д. Симонов-Емельянов. Адсорбция эпоксидианового
олигомера ЭД-20 и строение граничного слоя на
стеклянной поверхности.
ХИМИЯ И ТЕХНОЛОГИЯ НЕОРГАНИЧЕСКИХ МАТЕРИАЛОВ
С.Ю. Стефанович, В.В. Фомичев, В.В. Коновалова, А.В. Мосунов,
Б.В. Милль. Колебательная, релаксационная и трансляционная
подвижность ионов Li+ в монокристалле LiNbGeO5.
М.В. Цыганкова, В.И. Букин, Е.И. Лысакова, А.Г. Смирнова.
Экстракция ванадия из сернокислых растворов N-(2-гидрокси-5нонилбензил)-
, -дигидроксиэтиламином.
© МИТХТ им. М.В. Ломоносова Abstract
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«Вестник МИТХТ», 2009, т. 4, № 1
Review
MITHT
1/2009
Редакция:
Агаянц И.М.
Наумова Ю.А.
Семерня Л.Г.
Середина Г.Д.
CONTENTS
TO 175-th ANNIVERSARY OF D.I. MENDELEEV
L.Yu. Alikberova. The Periodic Law and Periodic System of
chemical elements.
A. Yu. Zakgeym. Mendeleyev and Borodin.
A.A. Ivanova. About some aspects of D.I. Mendeleev's worldoutlook.
S.M.
Sukhorukova, A.K. Frolkova, K.K. Necheuhin. D.I. Mendeleev as
the founder of socio-ecological-economic approach to development
of industry in Russia.
CHEMISTRY AND TECHNOLOGY OF ORGANIC SUBSTANCES
V.P. Vislovsky, R.M. Talyshinsky, V.F. Tretyakov, N.A. Frantsuzova,
V.E. Shejnin. Isobutane dehydrogenation by oxidizing in
isobutene on Ni-V-Sb/γAl2O3 catalytic system.
Yu. B. Kirillov, N.M. Klimenko. Non-empirical calculations for
minimal energetic reaction pathways of HF molecule addition to
acetylene and methylacetylene.
Адрес редакции:
119571, г. Москва,
пр. Вернадского, 86,
к. Л-119
телефон: (495) 936-82-88
e-mail: vestnik@mitht.ru
S.A. Makarova, I.S. Levacheva, I.A. Grickova, M.A. Sakvarelydze,
A.E. Harlov, S.M. Levachev. Influence of ammonium sulfate on the
properties of 2D films, made from polysterol microsphere.
D.S. Sidorenko, A.V. Vovk, S.A. Kutylev, G.M. Kuzmicheva,
A.B. Dubovski. Producing and studying of carbon nanotubes.
THEORETICAL BASED OF CHEMICAL TECHNOLOGY
M.K. Zakharov. Energy consumption and energy saving while
separation liquid mixtures by distillation methods.
G.A. Nosov, M.E. Uvarov, V.M. Miasoedenkov. Cryctallization of
substances from admixtures with employment of calorific pumps
А.А. Smirnykh. Features of construction of a measuring rotation
devices cell for measurement viscosity.
Подписано в печать
19.02.2009 г. Формат 60x90/8.
Бумага офсетная.
Гарнитура Times.
Печать офсетная.
Уч. изд. листов 4,4.
Заказ № 32.
Тираж 500 экз.
А.А. Smirnykh. Improvement Gepler viscousimetr for research
of the liquids with high optical density and viscosity.
SYNTHESIS AND PROCESSING OF POLYMERIC COMPOSITES
M.A. Polunina, V.A. Tverskoy, N.V. Dorofeeva. Gas separated
properties of membranes with diffusive layers from N-alkylated
poly(vinyl pyridine) and its complexes with sodium dodecyl
sulfate.
B.V. Pokidko, E.F. Bukanova, I.A. Tutorsky, M.B. Il`ina. Influence
of Ca2+ on the adsorption of different surfactants in the
bentonite-water interface.
Отпечатано с оригинал-макета в
«ГЕЛИОПРИНТ»
119602, Москва, Ак. Анохина, 38, к. 1
A.N. Trofimov, O.Y. Bryksina, V.M. Komarov, V.S. Kopytin,
G.A. Simakova, I.D. Simonov-Emeljanov. Adsorption of epoxy
oligomer ED-20 and structure interfacial layer on the glass surface.
CHEMISTRY AND TECHNOLOGY OF INORGANIC MATERIALS
S.Y.Stefanovich, V.V.Fomitchyov, V.V. Konovalova, A.V. Mosunov,
B.V. Mill. Oscillating, relaxating, and translating mobility of Li+
ions in the LiNbGeO5 monocrystal.
M.V. Tsygankova, V.I. Bukin, E.I. Lisakova, A.G. Smirnova. The
extraction of vanadium from sulfuric solutions by N-(2-hydroxy-5nonylbenzyl)Abstract
-dihydroxyethylamin.
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«Вестник МИТХТ», 2009, т. 4, № 1
ABSTRACT
L.Yu. Alikberova. Periodic Law and Periodic system of chemical elements.
The earliar attempts chemical of elements’ classifications were usually based on their properties.
Since chemical properties are very complex and diverse, so that classifications were
unsuccessful. The first step to creation Mendeleev’s periodic system for chemical elements
became using of related atomic weights.
A. Yu. Zakgeym. Mendeleyev and Borodin.
It is told about friendship of two great Russian and worldwide cultural workers Dmitry I.
Mendeleyev and Alexander P. Borodin.
A.A. Ivanova. About some aspects of D.I. Mendeleev's world-outlook.
In this paper, the section "World outlook" of D.I. Mendeleev's book "Cherished Thoughts" is
analyzed. It is shown, what, in Mendeleev's opinion, is the connection between philosophy and
science, how important the problem was for him.
S.M. Sukhorukova, A.K. Frolkova, K.K. Necheuhin. D.I. Mendeleev as the founder of socioecological-economic
approach to development of industry in Russia.
Dmitri Mendeleev (1834-1907) - is the first scientist-chemist and an economist who identified the
entire range of socio-ecological-economic problems of industrial production, identifying ways of
their technological and socio-economic solutions. The relevance of his ideas persisted.
V.P. Vislovsky, R.M. Talyshinsky, V.F. Tretyakov, N.A. Frantsuzova, V.E. Shejnin. Isobutane
dehydrogenation by oxidizing in isobutene on Ni-V-Sb/γAl2O3 catalytic system.
Addition of nickel oxide in the V-Sb/γAl2O3 catalytic system, used in oxidative dehydrogenation of
isobutane, significantly increases conversion (from 36 to 42-44%) at isobutene selectivity of 70 %.
The developed catalysts consisting of systems V-Sb-O and V-Sb-Ni-O were characterized using
XRD, XPS, and H2-TPR. Formation of the discovered nickel vanadate phase NiV2O6 is as a result
of free phase VOx is a more effective catalyst due to increase in the quantity of mobile oxygen
lattice. It is suggested that the set of various vanadium surface phases improves activity and
selectivity of the new catalytic systems.
Yu.B. Kirillov, N.M. Klimenko. Non-empirical calculations for minimal energetic reaction
pathways of hf molecule addition to acetylene and methylacetylene.
Potential energy surfaces of gas-phased synchronous addition of HF to acetylene and
methylacetylene. A non-empirical Harthree-Fock-Ruthane method (Gaussian-03, G-31++G**
basis) with electronic correlation consideration in MP2 approximation (Moeller-Plesseth 2nd grade)
was used. Reaction heats and activation energies were calculated. Reaction heat of HF addition
to acetylene molecule is -19.5 kcal/mol, activation energy is 52.3 kcal/mol. Reaction heats of HF
addition to methylacetylene according to Markovnikov’s rule and against it comprise -20.7 and -
16.1 kcal/mol; activation energies are 48.0 and 53.5 kcal/mol accordingly. It was established that
HF addition to methylacetylene molecule with formation of 2-fluoropropene is more energetically
advantageous according to Markovnikov’s rule kinetically as well as thermodynamically.
S.A. Makarova, I.S. Levacheva, I.A. Grickova, M.A. Sakvarelydze, A.E. Harlov, S.M. Levachev.
Influence of ammonium sulfate on the properties of 2D films, made from polysterol microsphere.
The influence of ammonium sulfate concentration in aqueous sybfase on the parameters of 2D films
was investigated. It was observe that, adding of electrolyte is causing the growth of parameters of
isotherm due to gidrophobisacia of microsphere because of changes in double electrical layer.
D.S. Sidorenko, A.V. Vovk, S.A. Kutylev, G.M. Kuzmicheva, A.B. Dubovski. Producing and
studying of carbon nanotubes.
Synthesis parameters of multiwall carbon nanotubes were prepared by catalytic pyrolysis of toluene and
isopropyl alcohol under isochome conditions in the presence of nickel oxalate as catalyst were investigated.
The synthesis products were analyzed by electron microscopy and x-ray diffraction spectroscopy.
M.K. Zakharov. Energy consumption and energy saving while separation liquid mixtures by
distillation methods.
Presented the new method of calculation of heat consumption while separation binary mixtures by
distillation methods. Studied the effect of complexity of separation of binary mixtures on necessary
heat consumption while separating them by distillation. It is shown that energy-saving in
rectification is increased when increasing the reflux ratio.
G.A. Nosov, professor, M.E. Uvarov, assistant, V.M. Miasoedenkov, associate. Cryctallization of
substances from admixtures with employment of calorific pumps.
Feasibility study of the crystallization of substances from admixtures process by the means of a
calorific pump with a closed cycle on the working substance is provided in this article. It is shown
that the usage of the calorific pump allows decreasing significantly power inputs for realization of
this process.
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«Вестник МИТХТ», 2009, т. 4, № 1
А.А. Smirnykh. Features of construction of a measuring rotation devices cell for measurement
viscosity.
With the purpose of research of the phenomena taking place of the initial stage of process
proposed the new original construction of measuring system rotational viscousimetr. The area of
possible application modernized viscousimetr devices is expanded.
А.А. Smirnykh. Improvement Gepler viscousimetr for research of the liquids with high optical
density and viscosity.
Addition of Gepler viscousimetr (VN-II) the new original constructive elements allow enlarge the
interval of possible application for research of the liquids with high optical density and viscosity.
The advanced construction of the device allows to increase accuracy of received results of
measurements.
M.A. Polunina, V.A. Tverskoy, N.V. Dorofeeva. Gas separated properties of membranes with
diffusive layers from N-alkylated poly(vinyl pyridine) and its complexes with sodium dodecyl
sulfate.
O2 and N2 permeability of membranes with diffusive layers from quaternary poly(vinyl pyridine)
and its complexes with sodium dodecyl sulfate was studied. The influence of a layer's chemical
structure on these gases selectivity separation was shown.
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B.V. Pokidko, E.F. Bukanova, I.A. Tutorsky, M.B. Il`ina. Influence of Ca2+ on the adsorption of
different surfactants in the bentonite-water interface.
Adsorption of surfactants of different nature on the bentonites/water interface and an influence of
Ca2+ ions on the adsorption characteristics were investigated. The data obtained from adsorption
isotherms were compared with RFA data. It was shown that cationic ABDMAC have a maximal
adsorption and vertical orientation to the basal space of montmorillonite. In the case of nonionic
oxyethylated alkylphenols molecules intercalate in to the interlayer and form bylaeyer structure
parallel to the surface even at high concentrations. Anionic surfactant did not penetrate into
interlayer and situated only on the external surface of bentonites. In the presence of calcium ions
adsorption increase witch lead to more compact vertical orientation of molecules.
A.N. Trofimov, O.Y. Bryksina, V.M. Komarov, V.S. Kopytin, G.A. Simakova, I.D. SimonovEmeljanov.
Adsorption of epoxy oligomer ED-20 and structure interfacial layer on the glass
surface.
Adsorption of epoxy oligomer ED-20 on the glass surface have investigated. Comparison
experimental and calculated on basis Landau-Lifshits theoretical model results indicated that
adsorption in studied system was polymolecular.
S.Y.Stefanovich, V.V.Fomitchyov, V.V. Konovalova, A.V. Mosunov, B.V. Mill. Oscillating, relaxating,
and translating mobility of Li+ ions in the LiNbGeO5 monocrystal.
Dielectric properties of single crystals of LiNbGeO5, crystallizing in the andalusite ( -Al2SiO5)
structure, have been studied. Dielectric and conducting properties along the major crystallographic
axes were investigated at frequencies from 1 to 1000 kHz and in the range of temperatures
between 100 and 600 K. Determined potential barriers between the equilibrium positions of Li+
ions are classified as low energy (0.23–0.79 eV, along the a axis) and high energy (0.9–1.90 eV,
along the a, b, and c axes). Additional interstitial sites with the distances between them 0.3–0.4 Е
have been found along the a axis, while no such sites observed along the b and c axes. Activation
energy (Ea) in the direction a is 0.47 eV and σa(570 K) = 2.10–5 S/cm, which correspond to the
super-ionic conductivity.
M.V. Tsygankova, V.I. Bukin, E.I. Lisakova, A.G. Smirnova. The extraction of vanadium from
sulfuric solutions by N-(2-hydroxy-5-nonylbenzyl)N-(2-hydroxy-5-nonylbenzyl)-dihydroxyethylamin.
-dihydroxyethylamin
is shown to appear the efficient extractant for
the extraction of vanadium from the weak acidic solutions. Basic regularities the extraction of
vanadium has been investigated. The re-extraction of vanadium from the organic phase by alkali
and ammonia solutions has been carried out.
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«Вестник МИТХТ», 2009, т. 4, № 1
Вестник МИТХТ
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