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по образованию
Вестник
МИТХТ
5/2008
октябрь
Научно-технический
журнал
«Вестник МИТХТ», 2008, т. 3, № 5
ISSN 1819-1487
СОДЕРЖАНИЕ
ХИМИЯ И ТЕХНОЛОГИЯ ОРГАНИЧЕСКИХ ВЕЩЕСТВ
И.Ю. Филатов, Ю.Н. Филатов, М.С. Якушкин. Электроформование
волокнистых материалов на основе полимерных микро- и
нановолокон. История, теория, технология, применение.
И.Б. Кравченко, А.Е. Корнев, Ю.А. Наумова, В.Г. Никольский,
И.А. Красоткина. Исследование эластичного наполнителя, получаемого
методом высокотемепреатурного сдвигового измельчения.
А.Н. Матвиенко, Ю.П. Мирошников. Оптимизация фазовой
морфологии для пористых материалов на основе многокомпонентных
смесей полимеров.
ТЕОРЕТИЧЕСКИЕ ОСНОВЫ ХИМИЧЕСКОЙ ТЕХНОЛОГИИ
Г.А. Григорьев. Изотерма адсорбции для смачивания твердого
тела жидкостью при иммерсионном смачивании.
Г.А. Григорьев. О термодинамическом методе описания процесса
смачивания.
Издается с февраля 2006 г.
Выходит один раз
в два месяца
Учредитель
МИТХТ им. М.В.Ломоносова
Ю.А. Писаренко, Д.М. Бирюков. Полистационарность в непрерывном
процессе равновесного открытого испарения с химической реакцией.
Л.А. Серафимов, Л.А. Хахин, А.К. Фролкова. Исследование энтропии
равновесного процесса дистилляции с последующей полной
конденсацией паров.
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ХИМИЯ И ТЕХНОЛОГИЯ ЛЕКАРСТВЕННЫХ ПРЕПАРАТОВ И БИОЛОГИЧЕСКИ
АКТИВНЫХ СОЕДИНЕНИЙ
Т.М. Буслаева, Е.В. Копылова, В.В. Кравченко, Г.А. Федорова.
Кристаллическая структура тиокарбамидного комплекса иридия.
Главный редактор:
Главный редактор:
проф. Тимофеев В.С.
Зам. главного редактора:
проф. Фролкова А.К.
проф. Фомичев В.В.
А.А. Горшков, В.А. Ломовской, З.И. Фомкина. Температурная
зависимость сдвигового модуля упругости твердого раствора PDHx.
Ф.Н.Карачевцев, В.А. Кутвицкий, О.В. Сорокина. Кинетические
закономерности взаимодействия висмутатноборатных стѐкол с
ортофосфорной кислотой.
Ф.Н.Карачевцев, В.А. Кутвицкий, О.В. Сорокина. Определение
металлов в сложных оксидных системах.
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ХИМИЯ И ТЕХНОЛОГИЯ ЛЕКАРСТВННЫХ СОЕДИНЕНИЙ И
БИОЛОГИЧЕСКИ АКТВНЫХ ВЕЩЕСТВ
Я.Ф. Аль Ансари, В.Е. Баулин, Е.В. Савинкина, А.Ю. Цивадзе.
Синтез мезо-тетразамещѐнных порфиринов, содержащих фосфорильные
и азофенильные группы.
79
В.В. Красильникова, Н.И. Пахарькова, В.И. Попенко, А.П. Каплун.
Использование нанодисперсий, полученных из экстракта бересты,
для солюбилизации плохо растворимых в воде веществ.
Редакционная коллегия:
доц. Биглов Р.Р.
проф. Дробот Д.В.
проф. Корнюшко В.Ф.
акад. РАН Кузнецов Н.Т.
акад. РАН Мирошников А.И.
проф. Мирошников Ю.П.
проф. Озерин А.Н.
проф. Серафимов Л.А.
проф. Сухорукова С.М.
проф. Тверской В.А.
акад. РАН Цивадзе А.Ю.
акад. РАМН Швец В.И.
доц. В.Д. Юловская
И.В. Куликова, Д.А. Мурадова, С.Н. Михайлов. Стабильность
3 , 5 -o-(тетраизопропилдисилоксан-1,3-диил)нуклеозидов в присутствии
кислот Льюиса.
К.В. Мартынова, И.Ю. Нагаев, С.И. Шрам, В.И. Швец, Н.Ф. Мясоедов.
Синтез и характеристика фотоактивных арилазидных производных
пептидов семакса и Pro-Gly-Pro.
С.Г. Романова, Г.А. Серебренникова, А.А. Штиль. Синтез, изучение
цитотоксических свойств и гемолитической активности катионных
глицеролипидов алкильного типа.
ХИМИЯ И ТЕХНОЛОГИЯ ОРГАНИЧЕСКИХ МАТЕРИАЛОВ
С.Н. Городский, А.В. Курдюков, О.Н.Темкин. Колебательный
режим в реакции карбонилирования пропаргилового спирта.
И.А. Грицкова, Е.Н. Левшенко; Е.Р. Мансурова; И.В. Хачатурян,
Н.И. Прокопов, Г.А. Симакова, В.М. Копылов. Полимеризация стирола
в присутствии кремнийорганических ПАВ различной природы.
© МИТХТ им. М.В. Ломоносова Abstract
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Стр.1
«Вестник МИТХТ», 2008, т. 3, № 5
Review
MITHT
CONTENTS
SYNTHESIS AND PROCESSING OF POLYMERIC COMPOSITES
I.Yu. Filatov, Yu.N. Filatov, M.S. Yakushkin. Electrospun fibrous
materials from polymer micro- and nanofibers. History, theory,
technology, application.
5/2008
Редакция:
Агаянц И.М.
Наумова Ю.А.
Семерня Л.Г.
Середина Г.Д.
I.B. Kravchenko, A.E. Kornev, Y.A. Naumova, G.V. Nikolsky,
I.A. Krasotkina. Research elastic filler received by method of hightemperature
shift crushing.
A.N. Matvienko, Yu.P. Miroshnikov. Optimization of phase morphology
for porous materials based on multicomponent polymer blends.
TEORETICAL BASED OF CHEMICAL TECHNOLOGY CHEMISTRY AND
G.A. Grigoriev. Isotherm of adsorption for wetting of a solid by liquid
at immersion wetting.
G.A. Grigoriev. On the thermodynamic method of description of the
wetting process.
Yu.A. Pisarenko, D.M. Biryukov. Multiple steady states in continuous
process of equilibrium open evaporation with chemical reaction.
L.A. Serafimov, L.A. Khakhin, A.K. Frolkova. Entropy research of
distilling equilibrium process with the subsequent complete vapours
condensation.
Адрес редакции:
119571, г. Москва,
пр. Вернадского, 86,
к. Л-119
телефон: (495) 936-82-88
E-mail: vestnik@mitht.ru
CHEMISTRY AND TECHNOLODY OF INORGANIC SUBSTANCES
T.M. Buslaeva, E.V. Kopylova, V.V. Kravchenko, G.A. Fedorov. The
crystal structure of iridium complex with thiocarbamide.
A.A. Gorshkov, V.A. Lomovskoy, Z.I. Fomkina. Temperature function
of the shear modulus of resilience of the solid solution PDHx.
F.N.Karachevtsev, V.A.Kutvitsky, O.V. Sorokina. Kinetic interaction
regularity of bismuth-boron glasses with orthophosphoric acid.
F.N. Karachevtsev, V.A. Kutvitsky. Luminescent definition transitional
elements in complex oxides systems.
Подписано в печать
16.10.2008 г. Формат 60x90/8.
Бумага офсетная.
Гарнитура Times.
Печать офсетная.
Уч. изд. листов 4,4.
Заказ № 382.
Тираж 500 экз.
CHEMISTRY AND TECHNOLOGY OF MEDICAL PRODUCTS AND
BIOLOGICALLY ACTIVE SUBSTANCES
Ya.F. Al Ansari, V.E. Baulin, E.V. Savinkina, A.Yu. Tsivadze.
Synthesis of meso-tetrasubstituted porphyrins, containing phosphoryl
and azophenyl group.
V.V. Krasil’nikova, N.I. Pakhar’kova, V.I. Popenko, A.P. Kaplun. The
use of nanodispersions prepared from birch bark extract for poor
soluble substances solubilization.
I.V. Kulikova, D.A. Muradova, S.N. Mikhailov. Stability of 3 , 5 -o(tetraisopropyldisiloxane-1,3-diyl)nucleosides
in the presence of Lewis
acids.
K.V. Martynova, I.U. Nagaev, S.I. Shram, V.I. Shvets, N.F. Myasoedov.
Synthesis and characteristic of photoactive arylazide semax and ProGly-Pro
peptide derivatives.
Отпечатано с оригинал-макета в
«ГЕЛИОПРИНТ»
119602, Москва, Ак. Анохина, 38, к. 1
CHEMISTRY AND TECHNOLODY OF ORGANIC MATERIALS
S.N. Gorodsky, A.V. Kurdiukov, O.N. Temkin. Oscillating regime in
carbonylation reaction of propargyl alcohol.
Y.A. Gritskova, E.N. Levshenko, E.R. Mansurova, I.V. Hachaturyan,
N.Y. Prokopov, G.A. Simakova, V.M. Kopylov. Polymerization of
styrene in the presence of different siliconorganic detergents.
Abstract
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S.G. Romanova, G.A. Serebrennikova, A.A. Shtil. Synthesis and study
of cytotoxic and hemolytic activity of cationic glycerolipids alkyl type. 101
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«Вестник МИТХТ», 2008, т. 3, № 5
ABSTRACT
I.Yu. Filatov, Yu.N. Filatov, M.S. Yakushkin. Electrospun fibrous materials from polymer micro- and
nanofibers. History, theory, technology, application.
This article is devoted to rapid development of such field of chemical fibers technology as electrospinning and
dealing with history and theoretical ways of process description.
I.B. Kravchenko, A.E. Kornev, Y.A. Naumova, G.V. Nikolsky, I.A. Krasotkina. Research elastic filler
received by method of high-temperature shift crushing.
Possibility of using elastic filler which received of the waste of tyres by conditions of high temperatures and
deformation is investigated in rubber technology. The presented part of work has been directed on studying
of morphological properties elastic filler, abilities to participation in vulcanization process elastomer material,
comparison given kind of filler with the products of recycling of the worn out tyres presented in the modern
market.
A.N. Matvienko, Yu.P. Miroshnikov. Optimization of phase morphology for porous materials based on
multicomponent polymer blends
Morphology of ternary polymer blend PVB/ PP//PS for porous materials preparation was studied. Dosages
providing maximum dispersity level and continuity of PVB phase in PP matrix were determined. PVB forming
co-continuous phase in PP was selectively leached resulted in porous material which can be used in a variety
of applications.
G.A. Grigoriev. Isotherm of adsorption for wetting of a solid by liquid at immersion wetting.
The fundamental equation of adsorption and the adsorption isotherm for the process of immersion wetting
are derived on the basis of Gibbs model. It is shown that in the case of low volatile surface-active component
it is possible to calculate its adsorption constants Amax and K at the solid-liquid border from the
experimentally measurable value of superficial activity of limiting wetting tension, obtained by the Wilhelmi
plate method on the basis of an integral equation similar to Shishkovski equation, with the subsequent
specification of the values of adsorption constants by the method of successive approximations. It is shown
that such calculation allows to calculate the adsorption constants for solids with small specific surface, when
the analytical method (based on the concentration decrease) is impossible to accomplish.
G.A. Grigoriev. On the thermodynamic method of description of the wetting process.
The thermodynamic method of description of the wetting process is suggested. Calculated formulae for the
definition of F (free energy variation), S (entropy variation), U (internal energy variation) were obtained
using the wetting process of a vertical plate. A suitable standard state is selected, the opportunity is shown
for using calculated values for the prediction of the mutual substitution of two nonmiscible liquids on the solid
surface. The possibility of application of the well-known thermodynamic relationships at such description of
the wetting process was discussed.
Yu.A. Pisarenko, D.M. Biryukov. Multiple steady states in continuous process of equilibrium open
evaporation with chemical reaction
There has been received mathematical description of continuous equilibrium evaporation process with
chemical reaction. The criterion of multiple steady states occurrence is determined. Their stability is
estimated and bifurcation diagrams are also constructed.
L.A. Serafimov, L.A. Khakhin, A.K. Frolkova. Entropy research of distilling equilibrium process with the
subsequent complete vapours condensation
Are investigated equilibrium differential evaporation process and process of complete condensation. Is
shown, that each of these processes can be theoretically submitted as reversible. A processes combination
in a sequence equilibrium vaporization - the total condensation even in case of components reversibility of
derivates entropy occurrence at the expense of an temperatures inequality appropriate to differential
equilibrium vaporization, and total condensation outlet temperature.
E.V.Kopylova, T.M.Buslaeva, V.V.Kravchenko, G.A.Fedorova. The crystal structure of Iridium Complex
with Thiocarbamide.
By interaction of water solutions of K3[IrCl6] and Thiocarbamide (Thio, SC(NH2)2) at heating the complex of
the composition [Ir(Thio)3Cl3] was synthesized. By the method of X-ray diffraction that the compound
crystallizes in the monoclinic crystal system with space group C2/c, a = 13.492(3) Å, b = 8.264(2) Å, c =
24.979(5) Å, β = 92.79(3) , V = 2782.00(1) Å3, Z = 8. The compound has a structure with two
crystallographically independent iridium atoms: the coordination sphere of the Ir(1) atom involves two Cl
atoms and four S atom, whereas the coordination sphere of the Ir(2) atom consists four Cl atoms and two S
atom. Coordination of molecules Thio to the Iridium is realized though the sulfur atom.
A.A. Gorshkov, V.A. Lomovskoy, Z.I. Fomkina. Temperature function of the shear modulus of resilience of
the solid solution PDHx.
Spectra of internal dissipation losses as a functions of the temperature and the shear modulus for the
polycrystal system of Pd and the solid solution of PdH has been received .These spectra had been
developed by the method of free vibrations Theoretical description of defect of the shear modulus basing on
the theory of unresilience is suggested.
F.N.Karachevtsev, V.A.Kutvitsky, O.V. Sorokina. Kinetic interaction regularity of bismuth-boron glasses
with orthophosphoric acid.
Have been carry out research of interaction kinetic of bismuth-boron glasses consisting of: 70% Bi2O3, 30%
B2O3; 70% Bi2O3, 27% B2O3, 3% MoO3; 70% Bi2O3, 26.94% B2O3, 3.06% GeO2 with 87% orthophosphoric acid. On
initial interaction stage (under 3 min) establish a quota be chemistry reaction. At increase time (higher 10 min) of
interaction primary role in heterogeneous process play stage of diffusion through lay at a surface.
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«Вестник МИТХТ», 2008, т. 3, № 3
F.N. Karachevtsev, V.A. Kutvitsky. Luminescent definition transitional elements in complex oxides systems.
Has been displayed possibility of luminescent determination of Re, Mo and W on effect of
extinction of luminescence Tb3+ and Sm3+. Presence of several lines of a luminescence at rareearth
elements has allowed to carry out quantitative definition of transition and trace elements at
their combined presence in complex oxide. The elative error of a method at most 0,08.
Ya.F. Al Ansari, V.E. Baulin, E.V. Savinkina, A.Yu. Tsivadze. Synthesis of meso-tetrasubstituted
porphyrins, containing phosphoryl and azophenyl group.
New meso-tetrasubstituted porphyrins of interest as heterotopic ligands were synthesized. Substances are
investigated by methods of electronic and IR-spectroscopy, МALDI-TOF mass-spectrometry, 1H NMR
spectroscopy and elemental analysis
V.V. Krasil’nikova, N.I. Pakhar’kova, V.I. Popenko, A.P. Kaplun. The use of nanodispersions prepared
from birch bark extract for poor soluble substances solubilization.
The method of poor soluble substances solubilization with the use of nanodispersions prepared from birch
bark extract is proposed. Optimal substance/carrier ratios for methylpheophorbide A, doxorubicin, silymarin
and silibinin have been determined.
I.V. Kulikova, D.A. Muradova, S.N. Mikhailov. Stability of 3 , 5 -o-(tetraisopropyldisiloxane-1,3-diyl)nucleosides in
the presence of lewis acids.
Trimethylsilyl trifluoromethanesulfonate catalyzes effective isomerization of 3 ,5 -O-(tetraisopropyldisiloxane1,3-diyl,TIPDS)nucleosides
in 1,2-dicloroethane at 0 C into 2 ,3 -O-TIPDS-derivatives to give 55-90% yields.
On the other hand 3 ,5 -O-TIPDS-nucleosides except for uridine derivative 1a were found to be stable in the
in the presence of tin tetrachloride and boron trifluoride etherate
K.V. Martynova, I.U. Nagaev, S.I. Shram, V.I. Shvets, N.F. Myasoedov. Synthesis and characteristic of
photoactive arylazide semax and pro-gly-pro peptide derivatives.
The photoaffine arylazide derivatives of peptides semax and Pro-Gly-Pro have been synthesized. It was shown that
these compounds have cytoptotective action in culture of PC12 cells under conditions of oxidative stress.
S.G. Romanova, G.A. Serebrennikova, A.A. Shtil. Synthesis and study of cytotoxic and hemolytic activity
of cationic glycerolipids alkyl type. Synthesis and study of cytotoxic and hemolytic activity of cationic
glycerolipids alkyl type.
The synthesis of new cationic ether glycerolipids, non-phosphoros analogues of edelfosine. Are investigated
cytotixic properties and hemolytic activity of the synthesized substances.
S.N. Gorodsky, A.V. Kurdiukov, O.N. Temkin. Oscillating regime in carbonylation reaction of propargyl alcohol.
In the system KI – PdI2 – CH3OH with O2 the oscillating regime of carbonylation reaction of new substrate –
propargyl alcohol was find out. The reaction products were identified, the limits of oscillating area was
determined and preliminary mechanism of process was proposed.
Y.A. Gritskova, E.N. Levshenko, E.R. Mansurova, I.V. Hachaturyan, N.Y. Prokopov, G.A. Simakova,
V.M. Kopylov. Polymerization of styrene in the presence of different siliconorganic detergents.
The characteristics of polymer suspensions received in the presence of different siliconorganic detergents
were compared. The polymer suspensions have the narrow distribution of particles by size and contain the
functional groups on their surface.
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Вестник МИТХТ
Журнал выходит один раз в два месяца и публикует обзоры и статьи по актуальным проблемам
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Московская государственная академия тонкой химической технологии им. М.В. Ломоносова (МИТХТ).
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