Федеральное агентство
по образованию
Вестник
МИТХТ
2/2008
апрель
ISSN 1819-1487
СОДЕРЖАНИЕ
ЭКОЛОГО-ЭКОНОМИЧЕСКИЕ ПРОБЛЕМЫ ХИМИЧЕСКИХ ТЕХНОЛОГИЙ
С.А. Семенов, К.З. Гумаргалиева, Г.Е. Заиков. Характеристики
процессов и особенности повреждения материалов техники
микроорганизмами в условиях эксплуатации.
Э.Ю. Булычев, Л.В. Миронов, С.М. Сухорукова. Химикотехнологические
решения проблемы твердых бытовых отходов и
их социо-эколого-экономические аспекты.
Е.А. Дѐмчева, М.В. Цариковская, Е.И. Хабарова, В.Б. Люкманов. Маркетинговый
мониторинг интернет-ресурсов биотехнологий и
интернет-рынка биотехнологических разработок экологического
назначения.
Научно-технический
журнал
Издается с февраля 2006 г.
Выходит один раз
в два месяца
А.Л. Таран, Е.В. Долгалѐв, А.Ю. Холин. Эколого-экономически
эффективные технологии производства азотсодержащих минеральных
удобрений, разработанные в МИТХТ.
ТЕОРЕТИЧЕСКИЕ ОСНОВЫ ХИМИЧЕСКОЙ ТЕХНОЛОГИИ
В.И. Жучков, А.В. Анисимов, С.А. Решетов, П.Г. Румянцев,
А.К. Фролкова. Исследование зависимости давления паров
диметилсульфоксида и перфторбензола от температуры.
Г.А. Носов, Г.А. Кесоян, Д.А. Попов. Контактная кристаллизация с
использованием охлажденных растворителей.
Л.А. Серафимов, А.В. Фролкова. Соблюдение первого закона
Коновалова в процессе ректификации с инертным газом.
А.К. Фролкова, Л.А. Хахин. Энтропийная оценка ректификации
бинарных смесей при различных вариантах расчѐта процесса.
Учредитель
МИТХТ им. М.В.Ломоносова
А.К. Фролкова, Л.А. Хахин, Т.В. Челюскина, Л.И. Черных. Изменение
температуры вдоль траекторий процесса равновесной
конденсации многокомпонентных смесей.
Т.В. Челюскина, А.В. Фролкова, Е.А. Шаронова. Реализация первого
закона Коновалова в бинарных двухфазных системах.
ХИМИЯ И ТЕХНОЛОГИЯ ЛЕКАРСТВННЫХ СОЕДИНЕНИЙ И
БИОЛОГИЧЕСКИ АКТВНЫХ ВЕЩЕСТВ
Н.А. Брагина, И.Н. Федулова, И.П. Ушакова, П.В. Дубовский, В.В. Чупин..Синтез
глицерофосфолипидов с полимериизуемыми группами
для формирования стабильных наночастиц.
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45
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62
66
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24
29
33
71
Н.Н. Иванова, И.Я. Логинова, Т.С. Соловьева. Некоторые особенности
окислительных процессов в жиросодержащих кондитерских изделиях. 76
С.А. Кедик, Е.И. Ярцев, И.Е. Станишевская, С.В. Федоров. Технология
получения сухого очищенного экстракта из листьев стевии.
79
А.А. Мезенцева, Н.А. Миронова, Е.В. Бурляева. Прогнозирование
максимума поглощения производных бактериохлорофилла а с
учетом конформационной гибкости молекул.
ХИМИЯ И ТЕХНОЛОГИЯ ОРГАНИЧЕСКИХ МАТЕРИАЛОВ
Ву Хон Шон, Н.Ю. Борисова, Е.Ю. Афанасьева, Г.А. Фомичева,
Т.П. Колобова, Е.Я. Борисова. Cинтез и свойства (±)-транс-2диалкиламиноэтиламиноциклогексанолов.
ЯЗЫКОЗНАНИЕ
Л.А.
Иванова. Типы референции и определенные дескрипции.
Е.Л. Лукомская. К вопросу о научной дискурсивной речи.
КРАТКИЕ СООБЩЕНИЯ
Е.А. Ларкина, Буй Т. Л. Ань, Е.П. Ткачевская, А.Ф. Миронов. Взаимодействие
феофорбида а с первичными алифатическими аминами.
© МИТХТ им. М.В. Ломоносова Abstract
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Стр.1
«Вестник МИТХТ», 2008, т. 3, № 2
Review
MITHT
2/2008
Редакция:
И.М. Агаянц
Ю.А. Наумова
Л.Г. Семерня
Г.Д. Середина
Адрес редакции:
119571, г. Москва,
пр. Вернадского, 86,
к. Л-119
телефон: (495) 936-82-88
E-mail - vestnik@mitht.ru
Подписано в печать
1.04.2008 г. Формат 60x90/8.
Бумага офсетная.
Гарнитура Times.
Печать офсетная.
Уч. изд. листов 4,4.
Заказ № 67.
Тираж 500 экз.
Отпечатано с оригинал-макета в
«ГЕЛИОПРИНТ»
119602, Москва, Ак. Анохина, 38, к. 1
CONTENTS
ECOLOGIGAL AND ECONOMIC PROBLEMS OF CHEMICAL TECHNOLOGIES
S.A. Semenov, K.Z. Gumargalieva, G.E. Zaikov. Process characteristics
and peculiarities of damages of materials by microorganisms in the
exploitation conditions.
E.J. Bulychev, L.V. Mironov, S.M. Sukhorukova. Chemical technological
decisions of the problem of firm household waste products and their
social, ecological and economic aspects.
E.A. Demcheva, M.V. Tsarikovskaya, E.I. Khabarova, V.B. Lukmanov.
Marketing monitoring of biotechnological internet resources and
internet market of ecology related biotechnological developments
A.L. Taran, E.V. Dolgalyov, A.J. Holin. Ecologyco-economically effective
technologys of produsing of nitrogen containing mineral fertilizers
developed in MITHT.
TEORETICAL BASED OF CHEMICAL TECHNOLOGY
V.I. Zhuchkov, A.V. Anisimov, S.A. Reshetov, P.G. Rumjantsev,
A.K. Frolkova. Study of the dependence of the pressure of vapors of
dimethylsulfoxide and perfluorinebenzene on the temperature.
G.A. Nosov, G.A. Kesojan, D.A. Popov. Contact crystallization with
using of cooled solution.
L.A. Serafimov, A. V. Frolkova. Konovalov's First Law Validity in
Reactive Distillation Processes With Inert.
A.K. Frolkova, L.A. Hahin. Entropic estimation of rectification binary
mixes at various variants of process computation.
A.K. Frolkova, L.A. Hahin, T.V. Chelyuskina, L.I. Chernyh. The
temperature change along trajectories of process of equilibrium
condensation of multicomponent mixtures.
T.V. Chelyuskina, A.V. Frolkova, Ye.A. Sharonova. Konovalov's first
law validity in binary two-phase systems.
CHEMISTRY AND TECHNOLOGY OF MEDICAL PRODUCTS AND
BIOLOGICALLY-ACTIVE SUBSTANCES
N.A. Bragina,
I.N. Fedulova,
I.P. Ushakova, P.V. Dubovskij,
V.V. Chupin. Synthesis of the glycerophospholipids with polymerizable
groups for the stable nanoparticles formation.
N.N. Ivanova, I.Y. Loginova, T.S. Solov’eva. Some features of
oxidative processes in fat-containing confectionary products.
S.A. Kedik, E.I. Jartsev, I.E. Stanishevskaja, S.V. Fedorov. Technology
of reception of the dry cleared extract from leaves stevia.
A.A. Mezentseva, N.A. Mironova, E.V. Burlyeva. Forecasting the
maximum absorption of bacteriochlorofyll a derivatives subject to
conformational flexibility of molecules.
CHEMISTRY AND TECHNOLOGY OF ORGANIC MATERIALS
Vu Hon Shon, N.Yu. Borisova, E.Yu. Afanasieva, T.P. Kolobova,
E.Ya. Borisova. Synthesis and properties of (±)-trans-2dialkylaminoethylaminocyclohexanols.
LINGUISTICS
L.A.
Ivanova. The types of reference and definite descriptions
E.L. Loukomskaya. On types of discurcive speech
SHORT COMMUNICATIONS
Е.А. Larkina, T.L.A. Bui, E.P. Tkachevskaya, A.F. Mironov. Interaction
between pheophorbide a and primary aliphatic amines.
Abstract
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Стр.2
ABSTRACT
S.A. Semenov, K.Z. Gumargalieva, G.E. Zaikov. Process characteristics and peculiarities of
damages of materials by microorganisms in the exploitation conditions.
The review gives some characteristics and methods of determination of microbiological
damages of materials (adhesion, growing of microbe cells and changing of material
properties under the action of microorganisms). These methods and characteristics give
quantitative estimation of damages process.
Authors of paper gave new method of microbiological damages investigation. This
investigation is including several microbiological, chemical, biochemical and mechanical
methods. It was shown that this complex of methods are very effective in case of
investigation of material samples damages.
E.J. Bulychev, L.V. Mironov, S.M.Sukhorukova. Chemical technological decisions of the problem
of firm household waste products and their social, ecological and economic aspects.
The analysis of defects of the ways for burial of solid waiste and tecnologies of incinerations,
combustion of solid waiste used in our country is represented. The concept of Universal
Biokompleks is offered for the purpose of ecological and есоnomic optimization of these
ways.
E.A. Demcheva, M.V. Tsarikovskaya, E.I. Khabarova, V.B. Lukmanov. Marketing monitoring of
biotechnological internet resources and internet market of ecology related biotechnological
developments.
The development grade of biotechnological branch is varies significantly according to
every different branch direction. One of such direction is the market of ecology related
biotechnological developments, which was monitored using marketing research in 20022006.
A.L.
Taran, E.V. Dolgalyov, A.J. Holin. Ecologyco-economically effective technologys of
produsing of nitrogen containing mineral fertilizers developed in MITHT.
In work the most modern and demanded in the industry ways of produsing of
technologically and ecologically safe nitrogen containing mineral fertilizers are presented.
This manufacture of Calcium -ammonium nitrate (CAN), supergranulated carbamide for
intrasoil entering and effective fertilizers mixturing, capsulated NK, NS, NPK fertilizers
with adjustable allocation of target components, etc.
V.I. Zhuchkov, A.V. Anisimov, S.A. Reshetov, P.G. Rumjantsev, A.K. Frolkova. Study of the
dependence of the pressure of vapors of dimethylsulfoxide and perfluorinebenzene on the
temperature.
Are obtained the experimental dependences of the pressure of the saturated vapor on the
temperature for the clean of dimethylsulfoxide and perfluorinebenzene in the range of
temperatures, that corresponds to extractive rectification under the atmospheric pressure.
3
19
G.A. Nosov, G.A. Kesojan, D.A. Popov. Contact crystallization with using of cooled solution.
The new technique of contact crystallization with using of cooled solvent has been
proposed and theoretically analyzed. This technique allows to exclude contamination of
separated products by coolants and to simplify its instrumentation.
Serafimov, A. V. Frolkova. Konovalov's First Law Validity in Reactive Distillation Processes With
Inert.
The questions of Distillation Process and Reactive Distillation Process into inert stream
are considered.
A.K. Frolkova, L.A. Hahin. Entropic estimation of rectification binary mixes at various variants of
process computation.
Optimization of power supply level of a two-unit rectification column on preproject stage of
development unit of division indissolubly is connected to used process computation
variant, which the certain set of explanatory variables answers. In clause production of
entropy is considered as criterion of an optimal arrangement of power supply at
rectification of binary mixes various nature. The analysis of entropy production is carried
out at design and verifying variants.
A.K. Frolkova, L.A. Hahin, T.V. Chelyuskina, L.I. Chernyh. The temperature change along
trajectories of process of equilibrium condensation of multicomponent mixtures.
The temperature change along trajectories of process of open equilibrium condensation is 27
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«Вестник МИТХТ», 2008, т. 3, № 2
investigated. The equation of temperature dependence along a trajectory of the open
equilibrium condensation, similar to Schreinemakers`rule is received.
T.V. Chelyuskina, A.V. Frolkova, Ye.A. Sharonova. Konovalov's first law validity in binary twophase
systems.
Complete conditions for the validity of Konovalov's first law in binary ideal and not ideal
two-phase systems are found.
N.A. Bragina, I.N. Fedulova, I.P. Ushakova, P.V. Dubovskij, V.V. Chupi. Synthesis of the
glycerophospholipids with polymerizable groups for the stable nanoparticles formation.
Synthesis of 1,2-di-(11,13-tetradecadienoyl)-sn-glycero-3-phosphocholine and 1,2-di(2,4-hexadienoyl)-sn-glycero-3-phosphocholine,
containing terminal polymerizable diene
groups has been carried out. It is supposed that using of synthesized phosphorlipids
mixtures followed by their polymerization will lead to formation of stable nanoparticles –
bicelles, which will be capable to exist in a wide range of concentration of mixed
components and resistant to organic solvents action.
N.N. Ivanova, I.Y. Loginova, T.S. Solov’eva. Some features of oxidative processes in fatcontaining
confectionary products.
The complex oxidative processes taking place in fat-containing products – pastes –
during storage are defined by their multiple compositions. Secondary products of
oxidation determined by the standard chemical method from the acid number value of the
fat can react with various organic substances of pastes. Character of oxidative processes
essentially depends on a state of foodstuff as heterogeneous disperse system.
S.A. Kedik, E.I. Jartsev, I.E. Stanishevskaja, Fedorov S.V. Technology of reception of the dry
cleared extract from leaves stevia.
The optimized method of reception of the dry cleared extract from leaves Stevia
rebaudiana Bertoni with the high contents steviozid is offered. Physical and chemical
properties of the dry cleared extract Stevia are investigated.
A.A. Mezentseva, N.A. Mironova, E.V. Burlyeva. Forecasting the maximum absorption of
bacteriochlorofyll a derivatives subject to conformational flexibility of molecules.
The relationship "structure – property" of the bacteriochlorofyll a derivatives has been
investigated. The prognostic procedure of thermodynamic and spectral characteristics for
group of these compounds has been offered.
Vu Hon Shon, N.Yu. Borisova, E.Yu. Afanasieva, T.P. Kolobova, E.Ya. Borisova. Synthesis and
properties of (±)-trans-2-dialkylaminoethylaminocyclohexanols.
This article is devoted method of synthesis and study of the properties of (±)-trans-2dialkylaminoethylaminocyclohexahols.
It was found that the studied compounds are not
toxic and have expressed antiarrhythmic properties. It was found that the explored
compounds are low-toxicity substances having pronounced antiarrhythmic properties.
L.A. Ivanova. The types of reference and definite descriptions.
The article deals with the study of the types of reference and definite descriptions. The
use of definite and indefinite reference is considered. The term «definite descriptions» is
interpreted. The attributive and referential use of definite descriptions is discriminated.
E.L. Loukomskaya. On types of discurcive speech.
The article describes some potentialities of the communicative process of students and
types of discurcive speech. The author analyses the tasks and purposes confronting a
foreign language teacher in training research workers.
Е.А. Larkina, T.L.A. Bui, E.P. Tkachevskaya, A.F. Mironov. Interaction between pheophorbide a
and primary aliphatic amines.
The effect of primary aliphatic amine structure and conditions (solvent, the presence of
tertiary amine) in course of its reaction with pheophorbide a and methylpheophorbide a
on the yield of the final product – chlorine е6-13-alkylamide has been shown.
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Вестник МИТХТ
Журнал выходит один раз в два месяца и публикует обзоры и статьи по
актуальным проблемам химической технологии и смежных наук. Журнал
основан в 2006 году. Учредителем журнала является Московская
государственная академия тонкой химической технологии им. М.В.
Ломоносова (МИТХТ).
Журнал входит в Перечень ведущих рецензируемых научных
журналов, в которых должны быть опубликованы основные научные
результаты диссертации на соискание ученой степени кандидата наук.
● К публикации принимаются материалы, содержащие результаты
оригинальных исследований, в виде полных статей, кратких сообщений, а
также авторские обзоры и прогнозно-аналитические статьи по актуальным
вопросам химической науки, в том числе по:
1. Теоретическим основам химической технологии
2. Химии и технологии органических веществ
3. Химии и технологии лекарственных препаратов и биологически
активных соединений
4. Синтезу и переработке полимеров и композитов на их основе
5. Химии и технологии неорганических материалов
6. Химии и технологии редких и рассеянных элементов
7. Математическим методам и информационным технологиям в
химии и химической технологии
8. Эколого-экономическим проблемам химических технологий.
● Электронная версия журнала (CD-ROM и Интернет) выходит с
февраля 2006 г.
● Хорошо подготовленные статьи выходят в свет не более чем через 4
месяца после поступления в редакцию.
Журнал в розничную продажу не поступает. Он распространяется на
территории Российской Федерации и стран СНГ по каталогу агентства
«Роспечать», индекс 36924. Подписка на журнал принимается в любом
почтовом отделении.
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