Chemistry 4 (2016 9) 483-495 ~ ~ ~ УДК 541.138.3: 541.49:546.94 Redox Properties of Heterometallic Osmium Cluster Compounds Galina V. Burmakina*a,b Vladimir A. Maksakovc,d a , Vladimir P. Kirinc,d , and Anatoly I. Rubayloa,b,е Institute of Chemistry and Chemical Technology SB RAS FRC “Krasnoyarsk Science Center SB RAS” 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia b Siberian Federal University 79 Svobodny, Krasnoyarsk, 660041, Russia cNikolaev Institute of Inorganic Chemistry SB RAS 3 Acad. <...> Lavrentiev, Novosibirsk, 630090, Russia d Novosibirsk State University 2 Pirogov, Novosibirsk, 630090, Russia е 50 Akademgorodok, Krasnoyarsk, 660036, Russia Received 13.08.2016, received in revised form 09.10.2016, accepted 21.11.2016 The redox properties of heterometallic anionic [Os3Fe(μ-H)(CO)13]– Cp* MOs3 (CO)10 , [Os3Co(CO)13]– and neutral (μ-H)(μ-Cl) (M = Rh, Ir) clusters were studied by electrochemical methods at platinum, glassed carbon and dropping mercury electrodes in acetonitrile and dichloromethane solutions. <...> It was established that redox transformations of these heterometallic clusters results in the elimination of M-containing (М = Fe, Co, Rh, Ir) fragments and the formation of homometallic trinuclear osmium clusters, which undergoes further electrochemical reactions. <...> All rights reserved * Corresponding author E-mail address: bgvicct@gmail.com, bgv@akadem.ru Krasnoyarsk Scientifi c Centre SB RAS # 483 # Galina V. Burmakina, Vladimir P. Kirin… <...> Redox Properties of Heterometallic Osmium Cluster Compounds Редокс-свойства гетерометаллических кластерных соединений осмия Г.В. Бурмакинаа,б В.А. Максаковв,г а , В.П. Киринв,г , , А.И. Рубайлоа.б,д Институт химии и химической технологии СО РАН ФИЦ «Красноярский научный центр СО РАН» Россия, 660036, Красноярск, Академгородок, 50/24 б Россия, 660041, Красноярск <...>