For citation: Lutovac M.V., Chulovskaya S.A., Kuzmin S.M., Parfenyuk V.I. Metal influence in porphyrine structure on kinetic of electrodeposition and morphology of hydroxyphenylporphyrins based films. <...> Лутовац Факультет бизнеса и промышленного менеджмента, Университет «Унион», ул. <...> Среднекраска, д. 4, Бараево, Белград, Сербия,11400 E-mail: lutovac@mail.ru Светлана Альбертовна Чуловская (), Сергей Михайлович Кузьмин (), Владимир Иванович Парфенюк Лаборатория «Новые материалы на основе макроциклических соединений», Институт химии растворов им. <...> Ключевые слова: 2H-5,10,15,20-тетракис(4-гидроксифенил)порфирин, Zn-5,10,15,20-тетракис(4-гидроксифенил)порфирин, электрополимеризация, морфология, кинетика UDC: 547.979.7+544.023 M.V. Lutovac, S.A. Chulovskaya, S.M. Kuzmin, V.I. Parfenyuk Mitar V. Lutovaс Faculty of Business and Industrial Management, University Union "Nikola Tesla", Belgrade, Serbia E-mail: lutovac@mail.ru Svetlana A. Chulovskaya, Sergey M. Kuzmin ( ), Vladimir I. Parfenyuk Laboratory of New Materials on the Basis of Macrocyclic Compounds, G.A. Krestov Institute of Solution Chemistry of RAS, Akademicheskaya st., 1, Ivanovo, 153045, Russia E-mail: chulovskaya@yandex.ru, smk@isc-ras.ru (), vip@isc-ras.ru 32 Изв. вузов. <...> Вып. 12 METAL INFLUENCE IN PORPHYRINE STRUCTURE ON KINETIC OF ELECTRODEPOSITION AND MORPHOLOGY OF HYDROXYPHENYLPORPHYRINS BASED FILMS The films formation via activated by oxygen electrochemical oxidation of hydroxyphenylporphyrin and its zinc complex in dimethyl sulfoxide media was demonstrated. <...> The different kinetics of deposition and morphologies of the films were observed. <...> During the film deposition the working electrode surface was passivated in case of porphyrin-ligand, and was not passivated in case of metal complex. <...> As a result, the electrochemical method leads to sufficiently thick films with a globular structure based on the metal complex and films o small thickness films and layered structure based on the porphyrin-ligand. <...> Key words: 2H-5,10,15,20-tetrakis(4-hydroxyphenyl)porphyrin, Zn-5,10,15,20-tetrakis(4-hydroxyphenyl)porphyrin, electropolymerization, morphology, kinetics Porphyrin based film materials are promising as an effective catalysts [1, 2], an active elements of sensor devices [3, 4], in creating of organic transistors [5, 6], LEDs [7], nonlinear optical transmitters [8] and electrochromic devices [9, 10]. <...> There are several methods for film materials fabrication [14-16]. <...> Formation <...>