Zimonina , Victor V. Verpekina , Oleg S. Chudina , , and Anatoly I. Rubayloa,b,c aInstitute of Chemistry and Chemical Technology SB RAS 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia b 50 Akademgorodok, Krasnoyarsk, 660036, Russia c Krasnoyarsk Scientifi c Center SB RAS Siberian Federal University 79 Svobodny, Krasnoyarsk, 660041, Russia Received 12.09.2015, received in revised form 26.02.2016, accepted 14.03.2016 The redox properties of new binuclear μ-vinylidene complexes Cp(CO)2RePt(μ-C1 [L = СO, L′ = PPh3 (1); L = СO, L′ = P(OPri )3 (2); L = L′ = PPh3 (3); L = L′ = P(OPri bonds affording vinylidene complex Cp(CO)2 )3 = C2 HPh)LL′ (4)] were studied by electrochemical methods at a platinum, a glassed carbon and a dropping mercury electrodes in acetonitrile solutions. <...> It was established that one-electron oxidation of 3 and 4 results in a cleavage of the Re-Pt and Pt-C1 RePt = C = CHPh and [PtLL′] fragments. <...> In contrast to complexes 3 and 4, one-electron oxidation of 1 and 2 is reversible, indicating the greater electrochemical stability of lasts relative to 3 and 4. <...> All rights reserved * Corresponding author E-mail address: bgv@akadem.ru # 13 # Galina V. Burmakina, Victor V. Verpekin… Redox Properties of Binuclear Rhenium-Platinum Vinylidene Complexes… Редокс-свойства биядерных рений-платиновых винилиденовых комплексов с фосфорсодержащими лигандами Г.В. Бурмакинаа,в О.С. Чудина , В.В. Верпекина , Р.О. Ергаевв , Д.В. Зимонина , А.И. Рубайлоа.б,в , аИнститут химии и химической технологии СО РАН Россия, 660036, Красноярск, Академгородок, 50/24 б Россия, 660036, Красноярск, Академгородок, 50 в Россия, 660041, Красноярск, пр. <...> Свободный, 79 Электрохимическими методами на платиновом, стеклоуглеродном и ртутном капельном электродах в ацетонитриле изучены <...>