Журнал Сибирского федерального университета
Journal of Siberian Federal University
Химия
Chemistry
Редакционный совет
академик РАН Е.А.Ваганов
академик РАН И.И.Гительзон
академик РАН В.Ф.Шабанов
чл.-к. РАН, д-р физ.-мат.наук
А.Г.Дегерменджи
чл.-к. РАН, д-р физ.-мат. наук
В.Л.Миронов
чл.-к. РАН, д-р техн. наук
Г.Л.Пашков
чл.-к. РАН, д-р физ.-мат. наук
В.В.Шайдуров
чл.-к. РАН, д-р физ.-мат. наук
В.В. Зуев
Editorial Advisory Board
Chairman:
Eugene A. Vaganov
Members:
Josef J. Gitelzon
Vasily F. Shabanov
Andrey G. Degermendzhy
Valery L. Mironov
Gennady L. Pashkov
Vladimir V. Shaidurov
Vladimir V. Zuev
Editorial Board:
Editor-in-Chief:
Mikhail I. Gladyshev
Founding Editor:
Vladimir I. Kolmakov
Managing Editor:
Olga F. Alexandrova
Executive Editor for Chemistry:
Boris N. Kuznetsov
Редактор И.А. Вейсиг Корректор Т.Е. Бастрыгина
Компьютерная верстка Е.В. Гревцовой
Подписано в печать 18.03.2011 г. Формат 84х108/16. Усл. печ. л. 8,7.
Уч.-изд. л. 8,2. Бумага тип. Печать офсетная. Тираж 1000 экз. Заказ 4244.
Отпечатано в ПЦ БИК СФУ. 660041 Красноярск, пр. Свободный, 82a.
CONTENTS / СОДЕРЖАНИЕ
Boris N. Kuznetsov, Irina G. Sudakova,
Alain Celzard, Natalia V. Garyntseva,
Natalia M. Ivanchenko and Andrey V. Petrov
Binding Properties of Lignins Obtained at Oxidative Catalytic
Delignification of Wood and Straw
– 3 –
Darya I. Chuikina,
Olga V. Serebrennikova, Larisa D. Stakhina,
Tatiana L. Nikolaeva and Irina V. Russkikh
Laboratory Simulation of the Effect of Oil-Displacement Systems
on the Composition and Properties of High-Paraffin Crude Oil
– 11 –
È.Ñ. Васильева, Ò.À. Êåíîâà, Â.Ë. Корниенко
}ле*2!%.,м,че“*%е %*,“ле…,е 2,%ц,=…=2%" =*2,"…/м,
-%!м=м, *,“л%!%д= …= .ле*2!%де ,ƒ д,%*“,д= “",…ц=
– 18 –
Е.В. Веприкова, Е.А. Терещенко,
Н.В. Чесноков, Б.Н. Кузнецов
b%л%*…,“2/е д!е"е“…%-C%л,“2,!%ль…/е
л,*",д=ц,, …е-2 …/. ƒ=г! ƒ…е…,L
– 27 –
Í.Â. Âîëîãäèí, Ï.Â. Фабинский, Â.À. Федоров
hƒ3че…,е C%л,2е!м,че“*%L !=“2"%!,м%“2, =це2,л=це2%…=2%"
.!%м= (III) , *%K=ль2= (III) " “ме“ . "%д/ “ …-C!%C=…%л%м ,
,ƒ%C!%C=…%л%м
– 38 –
“%!Kе…2/ дл
2011 4 (1)
Стр.1
Editorial board for Chemistry:
Nikolai V. Chesnokov
Lubov ’ K. Altunina
Natalia G. Bazarnova
Vasiliy A. Babkin
Vicente Cebolla
Viktor M. Denisov
Zinfer R. Ismagilov
Sergey V. Kachin
Sergey D. Kirik
Wolfgang Klose
Vladimir I. Kovalchuk
Vladimir A. Likholobov
Yuri L. Mikhlin
Gennady L. Pashkov
Anatoly I. Rubailo
Tatyana V. Ryazanova
Vladimir A. Sobyanin
Valeri E. Tarabanko
Tatyana G. Shendrik
Maxim L. Shchipko
Jean V. Weber
С.Д. Кирик, В.А.Парфенов
c,д!%2е!м=ль…=
3“2%Lч,"%“2ь
– 50 –
Í.Í. Ãîëîâíåâ, Ñ.Ä. Êèðèê, Ä.Î. Криницын
q,…2еƒ , “"%L“2"= “%ед,…е…,L .…!%-л%*“=ц,…=
– 73 –
Е.О. Игнатьева, Е.М. Дворянова, И.К. Гаркушин
Š!е.*%мC%…е…2…= “,“2ем= Na2
MoO4
– 83 –
Å.Ñ. Семиченко, Â.Å. Çàäîâ, À.Â. Лесничев
j,…е2,че“*%е
,““лед%"=…,е
– 89 –
Свидетельство о регистрации СМИ
ПИ № ФС77-28-726 от 29.06.2007 г.
Серия включена в «Перечень ведущих
рецензируемых научных журналов
и изданий, в которых должны
быть опубликованы основные научные
результаты диссертации на
соискание ученой степени доктора и
кандидата наук» (редакция 2010 г.)
À.Î. Åðåìèíà, Â.Â. Ãîëîâèíà,
Н.В. Чесноков, Б.Н. Кузнецов
rгле!%д…/е =д“%!Kе…2/ ,ƒ г,д!%л,ƒ…%г% л,г…,…= дл %ч,“2*,
“2%ч…/. "%д %2 %!г=…,че“*,. C!,ме“еL
– 100 –
3-г,д!%*“,м,…%-2,4-Cе…2=…д,%…= “ =це2%…%м
д,ге*“,л=м,…%м
ц,*л%*%…де…“=ц,,
,
$ NaF $ NaI
“,л,*=2= lql-41 “ 2%ч*, ƒ!е…,
-%!м,!%"=…,
меƒ%“2!3*23!,!%"=……%г%
2!=е*2%!,, ег%
Стр.2
Journal of Siberian Federal University. Chemistry 1 (2011 4) 3-10
~ ~ ~
УДК 631.0.861.16
Binding Properties of Lignins Obtained
at Oxidative Catalytic Delignifi cation
of Wood and Straw
Boris N. Kuznetsova, c
Alain Celzardb
Natalia M. Ivanchenkoa
,* Irina G. Sudakovaa
, Natalia V. Garyntsevaa
and Andrey V. Petrova
,
,
a Institute of Chemistry and Chemical Technology SB RAS,
42 K. Marx, Krasnoyarsk, 660049 Russia
b
27 rue du Merle Blanc, BP 1041, F-88051 Epinol cedex 9, France
c
IJL-UMR UHP-CNRS 7198, ENSTIB,
Siberian Federal University,
79 Svobodny, Krasnoyarsk, 660041 Russia 1
Received 4.03.2011, received in revised form 11.03.2011, accepted 18.03.2011
Composition and binding properties of acetic acid lignins obtained at oxidative catalytic delignifi cation
of different types of plant biomass (softwood, hardwood, wheat straw) in the medium: acetic acid –
hydrogen peroxide – water – sulfuric acid catalyst were compared.
Obtained acetic acid lignins have high concentration of reactive oxygen-containing functional groups,
therefore they can be used as low-toxic binding agent for production of wood panel materials with
good strength characteristics. The infl uence of lignin nature, its content in lignin/wood blend and
conditions of pressing on the bending strength and water-resistance of obtained wood panel materials
was studied. Optimal technological parameters for manufacture of strong and water steady wood
panels were found.
Keywords: acetic acid lignins, composition, biding properties, wood pressed materials.
Introduction
At present the development of modern ecology safe composite materials on the basis of available
and inexpensive binding agents with low toxicity is a very important task. Some example of the use for
producing composite materials with improved characteristics the non-toxic binding agents on the base
of wastes of plant raw materials processing are available in literature [1, 2]. The most large-tonnage
waste materials of pulp and hydrolysis plants are industrial lignins.
* Corresponding author E-mail address: inm@icct.ru
1
© Siberian Federal University. All rights reserved
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