Журнал Сибирского федерального университета
Journal of Siberian Federal University
Химия
Chemistry
Редакционный совет
академик РАН Е.А.Ваганов
академик РАН К.С.Александров
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академик РАН В.Ф.Шабанов
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А.Г.Дегерменджи
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В.Л.Миронов
чл.-к. РАН, д-р техн. наук
Г.Л.Пашков
чл.-к. РАН, д-р физ.-мат. наук
В.В.Шайдуров
чл.-к. РАО, д-р физ.-мат. наук
В.С. Соколов
Editorial Advisory Board
Chairman:
Eugene A. Vaganov
Members:
Kirill S. Alexandrov
Josef J. Gitelzon
Vasily F. Shabanov
Andrey G. Degermendzhy
Valery L. Mironov
Gennady L. Pashkov
Vladimir V. Shaidurov
Veniamin S. Sokolov
Editorial Board:
Editor-in-Chief:
Mikhail I. Gladyshev
Founding Editor:
Vladimir I. Kolmakov
Managing Editor:
Olga F. Alexandrova
Executive Editor for Chemistry:
Boris N. Kuznetsov
Компьютерная верстка И.В. Гревцовой
Подписано в печать 02.03.2007 г. Формат 60х84/8. Усл. печ. л. 13,0.
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Отпечатано в ИПК СФУ. 660041 Красноярск, пр. Свободный, 79.
CONTENTS / СОДЕРЖАНИЕ
Boris N. Kuznetsov, Nikolai V. Chesnokov,
Nadezhda M. Mikova and Tatyana G. Shendrik
Palladium Catalysts on Carbon Supports Prepared from
a Natural Graphite and Anthracite
– 3 –
Victor I. Sharypov, Natalia G. Beregovtsova,
Boris N. Kuznetsov, Sergei V. Baryshnikov
and Jean V. Weber
The Scope for Distillable Liquids Generation from Biomass
and Plastics Waste Via Pyrolysis
– 15 –
Meghan Swanson, Vladimir V. Pushkarev,
Vladimir I. Kovalchuk and Julie L. d’Itri
Evidence for CO Disproportionation over Ceria during Oxygen
Storage Capacity Measurements: an in Situ Raman Spectroscopic
Investigation
– 24 –
Valeri E. Tarabanko, Mikhail Yu. Chernyak
and Marina A. Smirnova
Sodium Hydrosulfate as the Catalyst for Carbohydrate
Conversion into the Levulinic Acid and 5-Hydroxymetylfurfural
Derivatives
– 35 –
Dmitriy O. Krynitsyn, Olga N. Kononova
and Natalya V. Maznyak
Anion Exchange Recovery of Gold (I) from Thiocyanate
Solutions in the Presence of Iron (III), Silver (I) and Some Non
Ferrous Metal Ions
– 50 –
2008 (1)
Стр.1
Editorial board for Chemistry:
Nikolai V. Chesnokov
Lubov ’ K. Altunina
Natalia G. Bazarnova
Vasiliy A. Babkin
Vicente Cebolla
Viktor M. Denisov
Zinfer R. Ismagilov
Sergey V. Kachin
Sergey D. Kirik
Klose Wolfgang
Vladimir I. Kovalchuk
Vladimir A. Likholobov
Yuri L. Mikhlin
Gennady L. Pashkov
Anatoly I. Rubailo
Tatyana V. Ryazanova
Vladimir A. Sobyanin
Valeri E. Tarabanko
Tatyana G. Shendrik
Maxim L. Shchipko
Jean V. Weber
Олег С. Чудин, Алла Б. Антонова, Нина И. Павленко,
Вильям А. Соколенко, Анатолий И. Рубайло,
Александр Д. Васильев, Олег В. Семейкин
u,м,
",…,л,де…%"/. *%мCле*“%". q%%K?е…,е
-C5
H5
)(CO)2
RePt(U-C=CHPh)(PPh3
– 60 –
17.
oе!"/L U-",…,л,де…%"/L *%мCле*“ “% “" ƒью Re-Pt:
“,…2еƒ, “Cе*2!%“*%C,че“*%е
(η5
Татьяна В. Шулимович, Ольга И. Наслузова,
Алексей М. Шор, Владимир А. Наслузов,
Анатолий И. Рубайло
j"=…2%"%-.,м,че“*,L
O3
(0001)
– 71 –
Светлана А. Кузнецова, Владимир Г. Данилов,
Ольга В. Яценкова, Наталья М. Иванченко
}*%л%г,че“*, Kеƒ%C=“…/L C!%це““ C%л3че…, целлюл%ƒ/
,ƒ д!е"е“,…/ Kе!еƒ/
– 80 –
Свидетельство о регистрации СМИ
ПИ № ФС77-28-726 от 29.06.2007 г.
Владимир А. Левданский
o!%д3*2/ *%…де…“=ц,, Kе23л,…%"%L *,“л%2/ “ …е*%2%!/м,
=л,-=2,че“*,м, =м,…=м, , =м,…%*,“л%2=м,
– 88 –
Тамара И. Когай
rл3чше……/L д"3.“2=д,L…/L ме2%д C%л3че…, Kе23л,…%"%L
*,“л%2/ ,ƒ Kе23л,…=
– 97 –
,““лед%"=…,е, “2!3*23!=
)2
!=“че2 “2!3*23!/ ,
.…е!г,,
…3*ле=ц,, …=…%!=ƒме!…/. *л=“2е!%" ƒ%л%2= …= C%"е!.…%“2,
α-Al2
Стр.2
Boris N. Kuznetsov, Nikolai V. Chesnokov… Palladium Catalysts on Carbon Supports Prepared …
Journal of Siberian Federal University. Chemistry 1 (2008) 3-14
~ ~ ~
УДК 544.478.32
Palladium Catalysts on Carbon Supports Prepared from
a Natural Graphite and Anthracite
Nadezhda M. Mikovab
a
b
Boris N. Kuznetsov, Nikolai V. Chesnokov*a
and Tatyana G. Shendrikc
Siberian Federal University,
,
79 Svobodny, Krasnoyarsk, 660041, Russia
Institute of Chemistry and Chemical Technology SB RAS,
42 K.Marx st., Krasnoyarsk, 660049, Russia
c
Institute of Physical-Organic and Coal Chemistry NAS,
70 R. Luxemburg st., Donetsk, 340114, Ukraine 1
Received 15.01.2008, received in revised form 15.03.2008, accepted 10.04.2008
Infl uence of the conditions of the carbon supports preparation from an expanded natural graphite and
chemically modifi ed anthracites on the formation of carbon porous structure, on the distribution and
sizes of supported palladium particles and their catalytic activity in liquid phase reactions of hexene-1
and cyclohexene hydrogenation has been studied. At the same reaction parameters and Pd content
the catalytic activity of different samples varies by more than 100 times. Besides, the activity of some
catalysts in hexene hydrogenation is much higher (up to 20 times) than that in cyclohexene hydrogenation
reaction. The possible reasons for observed differences in Pd catalyst behavior are analysed.
Keywords: palladium catalyst, carbon support, expanded graphite, anthracites, chemical modifi cation,
hexene and cyclohexene hydrogenation.
Introduction
Rather high cost of synthetic active
carbons can restrict the scale of carbon supports
application in the industrial catalysis. At the same
time the signifi cant resources of inexpensive raw
materials, presented by natural graphites and
anthracite are not suffi ciently used for the catalyst
supports manufacture.
Relatively low reaction ability of natural
graphites towards the activation agents (steam,
oxygen, carbon dioxide) can make problems
in the preparation of porous carbon supports on
their basis. But graphites are able to form graphite
* Corresponding author E-mail address: cnv@icct.ru
1
© Siberian Federal University. All rights reserved
# 3 #
intercalated compounds which can suffi ciently
(by hundreds times) increase their volume after
a high temperature treatment [1]. This unique
property of intercalated graphites was used for
manufacturing thermally expanded graphites. The
latter have found an application in the production
of various non-porous carbon products. The
expanded graphites also have good prospects for
their use in the preparation of carbon sorbents [2,
3] and catalyst supports [4-7]. At present a wide
variety of graphite intercalated compounds is
known and different methods are used for their
synthesis. These conditions are favorable for
Стр.3