ПРОМЕДИА: М.
The salt (?5-pentamethylcyclopentadienyl){bis(pentafluorophenyl)thiomethylphenylphosphine-k2S,P)chloroiridium(III) tetrafluoroborate, [(?5-C5Me5)IrC{ k2S,P-(C6F5)2PC6H4SMe-2}]BF4 ,crystallizes as a conglomerate in the orthorhombic crystal system in space group P212121 with unit cell parameters a = 9.9621(9)?,b= 16.7793(15) ?, c = 18.5040(16) ?, V= 3093.1(5) ?3, Z = 4, dcalc = 2.014 g • cm–3. The structure of the SIr, SS stereoisomer reveals three-legged piano stool geometry about Ir, with Cp*—Ir, Ir—P, Ir—S and Ir—Cl distances of 1.847(5), 2.2791(14), 2.3451(13) and 2.3840(12) ? respectively.